The Research of Nitric Oxide Detection Using Nafion poly N ′, N ″-(1, 3-propanediyliene)bis(1, 2-benzene diamino N, N ′, N ″, N′″- Nickel Microsensor

Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (6): 866.

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The Research of Nitric Oxide Detection Using Nafion poly N ′, N ″-(1, 3-propanediyliene)bis(1, 2-benzene diamino N, N ′, N ″, N′″- Nickel Microsensor

XIAN Yue-Zhong, YING Xiang-Yang, ZHANG Wen, LUO Min, JIN Li-Tong 

College of Chemistry and Life Science, East China Normal University, Shanghai, 200062

Received:1997-08-11 Online:1998-06-24 Published:1998-06-24

Abstract

Abstract: This report describes the development of a simple, easy to fabricate, sensitive, and stable nitric oxide sensor. The sensor is based on the N ′, N ″-(1, 3-proanediyliene)bis(1, 2-benzene diamino-N, N ′, N ″, N′″-nickel(Ni(Ⅱ)L) mediator is electropolymerized on a platinum, Nafion-modified microelectrode(diameter 15 μm). The detection of NOis based on the Ni(Ⅱ)Lcatalysis of NOoxidation at an anodic potential of +0.74 V. The electrocatalytic oxidation mechanism is also discussed. The Ni(Ⅱ)L modified microelectrode was used to monitor NOin human blood, the results suggest that the sensor can detect NOin vitro .

Key words: Nitric oxide, NO detection, Nafion-polyNi(Ⅱ)L modified microelectrode

CLC Number:

O657.1

TrendMD:

XIAN Yue-Zhong, YING Xiang-Yang, ZHANG Wen, LUO Min, JIN Li-Tong  . The Research of Nitric Oxide Detection Using Nafion poly N ′, N ″-(1, 3-propanediyliene)bis(1, 2-benzene diamino N, N ′, N ″, N′″- Nickel Microsensor[J]. Chem. J. Chinese Universities, 1998, 19(6): 866.

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The Research of Nitric Oxide Detection Using Nafion poly N ′, N ″-(1, 3-propanediyliene)bis(1, 2-benzene diamino N, N ′, N ″, N′″- Nickel Microsensor

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