CJCU

Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (4): 629.

• Articles • Previous Articles     Next Articles

Synthesis, Crystal and Molecular Structure of Complex [Cu2(Gly GlyO)2(4,4′ bpy)(OH)2]·10H2O

GUO Xiu-Ying1, ZHANG Wen-Xiang2, CUI Ai-Li2, SHEN Lian-Chun2, WANG Feng-Shan2, LI Zhi-Ying3   

  1. 1. Department of Applied Chemistry, Inner Mongolia Teachers′College for Nationalities, Tongliao, 028000;
    2. Department of Chemistry, Jilin University, Changchun, 130023;
    3. Department of Applied Chemistry, Jilin Universityof Technology, Changchun, 130026
  • Received:1997-06-20 Online:1998-04-24 Published:1998-04-24

PDF (PC)

Abstract: A novel binuclear cupric complex with Gly-GlyO chelate ring and 4,4′-dipyridyl as an intermediate radical was synthesized by the reaction of 4,4′-dipy-ridyl and cupric nitrate in aqueous solution. The structural formula of the complex was confirmed as [(H2NCH2CONHCH2COO)(C10 H8N2)Cu(OH)(H2NCH2CONHCH2COO)]·10H2O by X-ray single crystal structure analysis. Crystallographic data are as follows: a triclinic system with a space group P1, a =0.7124(2) nm, b =1.1405(1) nm, c =1.1434(1) nm, α=67.65°, β=79.02°, γ=77.97°, V =0.834(3) nm3, Z =1. The structural data were refined by the block matrix least squares program to final Rvalue of 00727.

Key words: Gly-GlyO, 4,4′-Dipyridyl, Intermediate radical, Cupric complex

CLC Number: 

TrendMD: