Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (12): 1915.

• Articles • Previous Articles     Next Articles

Rare Earth Complexes with Ge-132 and Their Catalytic Hydrolysis to Phosphatide Bond of Mononucleotide

WANG Zhi-Qiang, CHEN Ji, ZHU Bing, ZHANG Shu-Gong   

  1. Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022
  • Received:1997-10-15 Online:1998-12-24 Published:1998-12-24

Abstract: The complexes of a series of rare earths with Ge-132 have been prepared. The carboxyl anions of Ge-132 molecule were coordinated to rare earth ion with chelate style. In the complexes molecule, the GeO3/2 group of Ge-132 were hydrolyzed to become Ge(OH)3 group, and later does not coordinate with rare earth ions. All of the complexes possess similar properties. In aqueous solution of pH6 and 50 ℃, these complexes can obviously selectively catalytically hydrolize the phosphatide bond of 5'-AMPand 5'-dAMPinto phosphatic acid and riboside.

Key words: Rare earth complex with Ge-132, 5'-AMP, 5'-dAMP, Catalysis hydrolysis

CLC Number: 

TrendMD: