Studies on Application of Microwave Heating Techniques for the Solid State Reactions of Coordination Compounds(Ⅰ)── Synthesis of Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ) Complexes by Solid State Reactions Under Microwave

Chem. J. Chinese Universities ›› 1997, Vol. 18 ›› Issue (9): 1432.

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Studies on Application of Microwave Heating Techniques for the Solid State Reactions of Coordination Compounds(Ⅰ)── Synthesis of Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ) Complexes by Solid State Reactions Under Microwave

JIA Dian-Zeng¹, YANG Li-Xin¹, XIA Xi¹, XIN Xin-Quan²

1. Department of Chemistry, Xinjiang University, Urumqi 830046;
2. Institute of Coordination Chemistry, Nanjing University, Nanjing 210093

Received:1996-07-19 Online:1997-09-24 Published:1997-09-24

Abstract

Abstract: Solid state reactions of the transition metal acetates such as Co (OAc)₂·4H₂O,Ni(OAc)₂·4H₂O,Cu (OAc)₂·H₂Owith organic compounds such as amino acids, Schiffbases, β-diketon, 8-hydroxyquinoline have been investigated in the microwave oven. It isshown that the coordination compounds can be synthesized by solid state reactions up to 50times faster in a microwave oven than by conventional techniques. The results suggest asignificant Potential value of microwave heating in solid state coordination chemistry.

Key words: Microwave radiation, Solid state synthesis, Solid state coordination reaction

CLC Number:

O611.4

TrendMD:

JIA Dian-Zeng, YANG Li-Xin, XIA Xi, XIN Xin-Quan. Studies on Application of Microwave Heating Techniques for the Solid State Reactions of Coordination Compounds(Ⅰ)── Synthesis of Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ) Complexes by Solid State Reactions Under Microwave[J]. Chem. J. Chinese Universities, 1997, 18(9): 1432.

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Studies on Application of Microwave Heating Techniques for the Solid State Reactions of Coordination Compounds(Ⅰ)── Synthesis of Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ) Complexes by Solid State Reactions Under Microwave

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