Chem. J. Chinese Universities ›› 1997, Vol. 18 ›› Issue (2): 250.

• Articles • Previous Articles     Next Articles

Theoretical Study on Secondary Bonding in Organo-metallic Compounds(Ⅲ)──The Feature of Structures and Secondary Bonding in Metallic Clusters Ions [M3 (CO)9CCO]2- (M=Fe, Ru, Os)

LAI Cheng-Ming, TANG Jun, YUAN Man-Xue, NIU Shu-Qiang   

  1. Department of Chemistry, Nankai University, Tianjin, 300071
  • Received:1996-12-19 Online:1997-02-24 Published:1997-02-24

Abstract: In this paper we discussed the features of structure of the metallic cluster anions [M3(CO)9CCO]2- and adoption of direction of the ligand (COO) to the metal atom and the secondary bonds by means of ICON(EHMO).

Key words: Metallic cluster, Secondary bonding, ICON(EHMO)

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