Chem. J. Chinese Universities ›› 1997, Vol. 18 ›› Issue (1): 73.

• Articles • Previous Articles     Next Articles

Application of Phenyl(phenylethynyl)iodonium Tosylate──Synthesis of Isopropylidene-5-alkyl-5-phenyle Malonates

ZHAO Jing-Guo1, CHEN Zhen-Chu2   

  1. 1. Department of Chemistry, Changzhi Medical College, Changzhi, 046000;
    2. Department of Chemistry, Hangzhou University
  • Received:1995-12-26 Online:1997-01-24 Published:1997-01-24

Abstract: Ageneral method for the synthesis of isopropylidene-5-alkyl-5-phenylemalonates via the reaction of phenyl (phenylethynyl)iodonium tosylate with isopropylidene 5-alkyl malonates in the presence of NaH/THF(or t-BuONa/t-BuOH, K2CO3/TEBA/CHCl3,K2CO3/18-Crown-6/THF) is reported in this paper.

Key words: Phenyl (phenylethynyl) iodonium tosylate, Isopropylidene-5-alkylmalonate, Iso-propylidene-5-alkyl- 5-phenylethynyl malonate

TrendMD: