Synthesis of Polystyrene with C60 in the Side Group

Chem. J. Chinese Universities ›› 1996, Vol. 17 ›› Issue (9): 1477.

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Synthesis of Polystyrene with C₆₀ in the Side Group

WANG Chang-Chun, SHU Chang, FU Shou-Kuan

Department of Macromolecular Science, Fudan University, Shanghai, 200433

Received:1995-09-26 Online:1996-09-24 Published:1996-09-24

Abstract

Abstract: Three-step reactions,i.e.,chloromethylation,azidization and cycloaddition,were adopted to introduce C₆₀ into the side group of polystyrene successfully, and each step reaction was discussed in detail.The products were proved to be extremely soluble in a variety of organic solvents such as CHCl₃, THF, etc..This solubility behavior is simillar to polystyrene itself and totally unlike C₆₀.

Key words: Chloromethylation, Azidization, Cycloaddition reaction, Polystyrene C₆₀ derivatives, C₆₀

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WANG Chang-Chun, SHU Chang, FU Shou-Kuan. Synthesis of Polystyrene with C₆₀ in the Side Group[J]. Chem. J. Chinese Universities, 1996, 17(9): 1477.

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Synthesis of Polystyrene with C₆₀ in the Side Group

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