Chem. J. Chinese Universities ›› 1996, Vol. 17 ›› Issue (5): 750.

• Articles • Previous Articles     Next Articles

The Syntheses of N,N'-Bis(aroylmethyl)-1,10-diaza-4,7,13,16-tetraoxacyclooctadecane

YU Jiang, XU Zhen-Hua, XU Guang-Xian   

  1. College of Chemistry and Molecular Engineering, Peking University, The State Key Laboratory of Rare Earth Material on Chemistry and Applications, Beijing 100871
  • Received:1995-05-10 Online:1996-05-24 Published:1996-05-24

Abstract: Two new kinds of organic macrocycle compounds were synthesized with different methods;N,N'-bis( a- phenacyl)-1,10-diaza-4,7,13,16-tetraoxacyclooctadecane(Ⅱ) and N,N'-bis(ω-acetothienone)-1,10-diaza-4,7, 13,16-tetraoxacyclooctadecane(Ⅱ).The fluorescent characteristics of compound Ⅱis better than that of traditional fluorescent ligand of a-thenoyltrifluoroacetone( HTTA).The probable reaction process in our work is also discussed.

Key words: Macrocycle, Cryptand[2,2], HTTA

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