Synthesis and Structures of the Complexes of β-Alkoxy-carbonylethyltin Trichlorides with N-Aryl-2-hydroxyacetophenylideneimines

Abstract

Abstract: Sixteen novel β-alkoxycarbonylethyltin trichlorides and the corresponding N-aryl-2-hydroxyacetophenylideneimines complexes have been synthesized and characterized.An Xray crystal structure analysis of the complex of β-methyloxycarbonylethyltin trichloride andN4methylphenyl-2-hydroxyacetophe has been performed.The crystal belongs to space group P1 The cell parameters are: a=1.0201 (6) nm, b=1.0822(4) nm, c= 1.3949(6) nm, a=99.88(3)°, β=98.63(4)°, γ=97.86(4)°, Z=2.The ligands coordinate to tin atom via phenolic oxygen atom.Coordination of carbonyl oxygen atom to tin atomstill exists in the complexes.The coordination number of tin atom is 6.

Key words: β-Alkoxycarbonylethyltin trichlorides.Schiff base, Complexes, Synthesis structure.

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BAO Ming, HE Qing-Lin, LIU Ji-Hong, LIU Bao-Dian, XING Yan, LIN Yong-Hua. Synthesis and Structures of the Complexes of β-Alkoxy-carbonylethyltin Trichlorides with N-Aryl-2-hydroxyacetophenylideneimines[J]. Chem. J. Chinese Universities, 1996, 17(4): 566.

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Synthesis and Structures of the Complexes of β-Alkoxy-carbonylethyltin Trichlorides with N-Aryl-2-hydroxyacetophenylideneimines

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