Synthesis and Investigation of Intermolecular Hydrogen Bonded Complexes Between 6-(4-Octyloxyphenyl-azophenoxy)-1-hexyl Polymaleicated and 4-(4-Heptanoxybenzoyloxy)-4'-stilbazole

Chem. J. Chinese Universities ›› 1996, Vol. 17 ›› Issue (12): 1940.

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Synthesis and Investigation of Intermolecular Hydrogen Bonded Complexes Between 6-(4-Octyloxyphenyl-azophenoxy)-1-hexyl Polymaleicated and 4-(4-Heptanoxybenzoyloxy)-4'-stilbazole

XU Xiao-He¹, TAIN Yan-Qing¹, CHEN Hao¹, WANG Yan-Yan¹, ZHAO Ying-Ying¹, TANG Xin-Yi¹, LI Tie-Jin¹, WANG Wei-Wei²

1. Department of Chemistry, Jilin University, Changchun, 130023;
2. School of Basic Medical Sciences, Capital University of Medical Sciences

Received:1995-12-03 Online:1996-12-24 Published:1996-12-24

Abstract

Abstract: In this paper,a new polymer 6-(4-octyloxyphenyl-azophenoxy)-hexyl polymaleicated (PMAN-OAB) was prepared;And intermolecular hydrogen bonded complexes between PMAN-OAB which acts as a proton donor and 4-( 4-heptanoxybenzoyloxy) -4'-stil-bazole(7SZ) which acts as a proton acceptor were studied. The results show that PMANOABis bilayer arrangement through intermolecular hydrogen bonding between carboxylic groups in its liquid crystalline state,its tilte angle at 118℃ is 39.3°,The results also show that the temperature ranges of the complexes containing 7SZfrom 40% to 90%are broader than those of PMAN-OAB and 7SZ.

Key words: Ester of polymaleic acid, Intermolecular hydrogen bond, Complexes

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XU Xiao-He, TAIN Yan-Qing, CHEN Hao, WANG Yan-Yan, ZHAO Ying-Ying, TANG Xin-Yi, LI Tie-Jin, WANG Wei-Wei. Synthesis and Investigation of Intermolecular Hydrogen Bonded Complexes Between 6-(4-Octyloxyphenyl-azophenoxy)-1-hexyl Polymaleicated and 4-(4-Heptanoxybenzoyloxy)-4'-stilbazole[J]. Chem. J. Chinese Universities, 1996, 17(12): 1940.

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Synthesis and Investigation of Intermolecular Hydrogen Bonded Complexes Between 6-(4-Octyloxyphenyl-azophenoxy)-1-hexyl Polymaleicated and 4-(4-Heptanoxybenzoyloxy)-4'-stilbazole

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