Chem. J. Chinese Universities ›› 1996, Vol. 17 ›› Issue (11): 1725.
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LI Bao-Guo1, A Juan2, BIAN Zhan-Xi1, ZHAO Hai-Ying1
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Abstract: The reaction between ferrocenylmethylaminoalcohols and chlorosilanes gave 12 compounds of ferrocenylmethylaminoalkoxy silanes in one-step method and in relatively good yield.The synthetic method and relationship between the water sensitivity and structures of the compounds were investigated.The experimental results show that both of the aminoalcohols FcCH2NHCH(R')CH(R″)OH(Fc=C5H5FeC5H4,R'=H,C2H5;R″=H,CH3)and chlorosilanes R(CH3)2SCl(R=CH3,C2H5,n-C3H7,n-C4H9)have influnce on the reaction.The more bulky R,R'and R″,the smaller the reaction rate.The title compounds FcCH2NHCH(R')CH(R″)OSi(CH3)2R,are relatively sensitive to water.The more bulky R,R'and R″,the more stable the compound to water.The structures were characterized by elementary analysis,IRand 1H NMR.
Key words: Ferrocenylmethylaminoalkoxy silane, Ferrocenylmethylaminoalcohol, Water sensitivity
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LI Bao-Guo, A Juan, BIAN Zhan-Xi, ZHAO Hai-Ying. Studies on Syntheses and Water Sensitivity of Ferrocenylmethylaminoalkoxy Silanes[J]. Chem. J. Chinese Universities, 1996, 17(11): 1725.
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http://www.cjcu.jlu.edu.cn/EN/Y1996/V17/I11/1725