Gas Phase Synthesis of Derivative of C60──C60S+

Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (8): 1280.

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Gas Phase Synthesis of Derivative of C₆₀──C₆₀S⁺

LIU Zi-Yang, HAO Guo-Lun, GUO Xing-Hua, LIU Shu-Ying

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022

Received:1995-03-07 Revised:1995-06-19 Online:1995-08-24 Published:1995-08-24

Abstract

Abstract: Gas phase ion-molecular reactions of C₆₀with the ion system of CS₂have been studied in the ion source of mass spectrometer.It was found for the first time that the sulfuric derivative of C₆₀──C₆₀S⁺was the main ions in the ion source,they did not react with C₆₀to form adduct ions due to their highly saturated structures.According to the dynamic analysis, the product ion came from the reaction of C₆₀with the fragment ion S⁺.The adduct ion may have the structure of epsulfide that is advantageous in energy.

Key words: C₆₀, CS₂, Ion-molecule reaction

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LIU Zi-Yang, HAO Guo-Lun, GUO Xing-Hua, LIU Shu-Ying. Gas Phase Synthesis of Derivative of C₆₀──C₆₀S⁺[J]. Chem. J. Chinese Universities, 1995, 16(8): 1280.

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Gas Phase Synthesis of Derivative of C₆₀──C₆₀S⁺

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