The XPS Study of Complex Oxides Eu0.5RE0.5Fe0.5Mn0.5O3

Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (3): 454.

• Articles • Previous Articles Next Articles

The XPS Study of Complex Oxides Eu_0.5RE_0.5Fe_0.5Mn_0.5O₃

REN Xiao-Lin¹, LI Li-Ping¹, WEI Quan²

1. Department of Chemistry, Department of Physics Analysis, Jilin University, Changchun 130023;
2. Measurement Center, Jilin University, Changchun 130023

Received:1994-05-18 Revised:1994-10-23 Online:1995-03-24 Published:1995-03-24

Abstract

Abstract: Complex oxides replaced by rare earth ions, Eu_0.5RE_0.5Fe_0.5Mn_0.5O₃(RE=La, Pr,Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb) were prepared by the solid state reaction method.Measurements by XRD and XPS were carried out. The study of XPS indicates that the replacement by rare earth causes the decrease of the binding energy(B. E. )of rare earth ions,compared to their sequioxides. And in the replaced oxides, the binding energy of Fe_{2p_3/2}and Mn_{2p_3/2} increases with the decrease of ion radius of REion. The reasons for the changes of B.E. are discussed.

Key words: Eu_0.5RE_0.5Fe_0.5Mn_0.5O₃, XPS, Changes of binding energy

TrendMD:

REN Xiao-Lin, LI Li-Ping, WEI Quan . The XPS Study of Complex Oxides Eu_0.5RE_0.5Fe_0.5Mn_0.5O₃[J]. Chem. J. Chinese Universities, 1995, 16(3): 454.

[1]	ZHANG Yong, FU Mao, WU Deli, ZHANG Yalei. Removal Performance and Mechanism of Selenite with the Highly Active Ferrous Hydroxyl Complex FHC(Cl^-)^† [J]. Chem. J. Chinese Universities, 2017, 38(5): 830.
[2]	SUN Er-Jun, WANG Dong, CHENG Xiu-Li, SHI Yu-Hua, SHI Tong-Shun. Preparation and Properties of 5,10,15,20-Tetra(4-myristylimidophenyl) Porphyrin and Its Zn and Mn Complexes [J]. Chem. J. Chinese Universities, 2007, 28(7): 1208.
[3]	ZHANG Ya-Nan^1,2, XIA Fan³, WANG Nü³, FENG Lin¹. Preparation and Characterization of Large-area Superhydrophobic Nanostructured Carbon Films [J]. Chem. J. Chinese Universities, 2007, 28(3): 568.
[4]	XIE Fu-Zhong¹, HU Hua-Rong¹, QIAO Ming-Hua¹, YAN Shi-Run¹, FAN Kang-Nian¹, LEI Hao², TAN Da-Li², BAO Xin-He², ZONG Bao-Ning³, ZHANG Xiao-Xin³. XPS Study on Adsorptive Desulfurization of Thiophene over Rapidly Quenched Skeletal Ni [J]. Chem. J. Chinese Universities, 2006, 27(9): 1729.
[5]	LI Ai-Ze, JIN Yu-Hui, LIU Bai-Jun, JIANG Zhen-Hua. Effect of Heat-treatment Atmosphere on the Near-infrared Absorption of the Fluorinated Poly(aryl ether) [J]. Chem. J. Chinese Universities, 2005, 26(6): 1177.
[6]	LI Hui, SHEN Fei, WU Chi-Fei. Preparation and Characterization of Novel NBR/PVC Alloy Crosslinked by Coordinate Bonds [J]. Chem. J. Chinese Universities, 2005, 26(2): 370.
[7]	LI Wan-Cheng, DU Guo-Tong, YANG Xiao-Tian, LIU Bo-Yang, ZHANG Yuan-Tao, ZHAO Bai-Jun, JIANG Xiu-Ying . XPS Valence Band of ZnO Films [J]. Chem. J. Chinese Universities, 2004, 25(11): 2078.
[8]	LI Xiao-Ling, XU Wei-Qing, JIA Hui-Ying, WANG Xu, ZHAO Bing, LI Bo-Fu . UV-Vis and XPS Spectroccopic Studies on Self-assembled Metalloporphrin Films [J]. Chem. J. Chinese Universities, 2004, 25(11): 2131.
[9]	YU Ji, CAN Hong-Yu, HE Yi, YUAN Juan, CHEN Huan-Lin. Studies on PVDF Hollow Fiber Affinity Membrane for Separation of γ-Globulin from Human Plasma(Ⅰ) -Preparation of PVDF Hollow Fiber Affinity Membrane and Its Adsorption Properties [J]. Chem. J. Chinese Universities, 2003, 24(5): 935.
[10]	DAI Wei-Lin, CAO Yong, FAN Kang-Nian, DENG Jing-Fa . In situ XPS Studies on the Anti-oxidation Effects of Nano-sized Ni-Co-B Amorphous Alloy [J]. Chem. J. Chinese Universities, 2003, 24(3): 473.
[11]	LI Li-Na, CHEN Yao-Qiang, GONG Mao-Chu, XIANG Yun . Catalytic Activity of Fe₂O₃/YSZ-γ-Al₂O₃for Methane Combustion [J]. Chem. J. Chinese Universities, 2003, 24(12): 2235.
[12]	SUN Bao-Yun, GU Zhen-Nan . Synthesis and Characterization of Water-soluble Metallofullerene Derivatives [J]. Chem. J. Chinese Universities, 2003, 24(10): 1747.
[13]	WU Xue-Yan, YOU Hong-Peng, ZENG Xiao-Qing, HONG Guang-Yan, KIM Chang-Hong, PYUN Chong-Hong, YU Byung-Yong, PARK Cheol-Hee. The Preparation of (La,Gd)PO₄:RE³⁺ (RE=Eu, Tb) by Co-precipitation Method and Their VUV Spectroscopic Properties [J]. Chem. J. Chinese Universities, 2003, 24(1): 1.
[14]	SONG Wei-Jie, ZHU Yong-Fa, CAO Li-Li, LI Zhan-Ping, WANG Dao-Yuan, Huang-Wei . Studies on Interface Structure of BBDMS-PPV/ITO System Using ADXPS Technique [J]. Chem. J. Chinese Universities, 2001, 22(5): 836.
[15]	LIU QingSheng, WANG ZhenLü, YU JianFeng, YANG PiaoPing, WANG GuoJia, YANG HongMao, ZHENG DaFang, WU TongHao. Investigation of Surface Structures of Supported ZnO/SiO₂ and ZnO-SiO₂ Sol-gel Catalysts [J]. Chem. J. Chinese Universities, 2001, 22(12): 2091.

The XPS Study of Complex Oxides Eu_0.5RE_0.5Fe_0.5Mn_0.5O₃

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments