Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (2): 252.

• Articles • Previous Articles     Next Articles

A Study of the Spectrum Properties and the Photovoltage Response of Nanocrystalline Nd2O3

CUI Yi1, WANG De-Jun1, WANG Bao-Hui1, LI Tie-Jin1, DONG Xiang-Ting2, HONG Guang-Yan2   

  1. 1. Department of Chemistry, Jilin University, Changchun, 130023;
    2. Institute of Applied Chemistry, Academia Sinica, Changchun
  • Received:1994-04-21 Revised:1994-07-10 Online:1995-02-24 Published:1995-02-24

Abstract: The diffuse reflectance spectra of nanocrystalline Nd2O3were measured in the ultraviolet-visible region.It is found that the part of f→f transition bands were widened and red-shift occurred.The absorption tail-band in the region from 300 to 550 nm was assigned to the O2p→Nd4ftransition.The behavior of light-induced charge transfer and photovoltaic properties of nanocrystalline Nd2O3were studied by the surface photovoltage spectroscopy(SPS) and electric field modulating SPStechniques.The SPSresponse shows two peaks at 330 nm(P1) and 380 nm(P2) in the UV-Vis range.The spectral features observed can be explained in terms of charge transfer and interband transition.

Key words: Nd2O3, Nanocrystalline, Surface photovoltage, Field modulation

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