Studies on the Catalytic Action of Imidazole and Its Derivativs in the Reactlon of β-Carotene Oxidative Decomposition

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (9): 1361.

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Studies on the Catalytic Action of Imidazole and Its Derivativs in the Reactlon of β-Carotene Oxidative Decomposition

ZHANG Zhi-Hui¹, CHEN Lan¹, ZHU Zhi-Ang¹, RUAN Wen-Juan¹, CHEN Rong-Ti¹, JIAN Dong-Qing²

1. Department of Chemistry, Nankai University, Tianjin, 300071;
2. Central Laboralory, Nankai University, Tianjin

Received:1993-10-09 Revised:1994-02-05 Online:1994-09-24 Published:1994-09-24

Abstract

Abstract: The catalytic action of imidazole and its derivatives in the reaction of β-carotene oxidative decomposition has been studied for employing meso-tetramesityl-porphinatoiron (Ⅲ) chloride(FeTMPCI)as the catalyst and m-chloroperbenzoic acid as the oxidant in dichloromethane by means of Beckmann Du-8Bspectrophotometer.Imidazole and its derivatives are not only the axial coordinate ligand but also a kind of catalyst.The reasonable mechnism of the reactions was postulated.The data were simulated with IBM-PCcomputer, the reaction rates were obtained. the effect of reaction condition on the rate of reaction was discussed.

Key words: Meso-tetramesityl porphinatoiron(Ⅲ)chloride, Imidazole, Reaction memchanism, β-Carotene

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ZHANG Zhi-Hui, CHEN Lan, ZHU Zhi-Ang, RUAN Wen-Juan, CHEN Rong-Ti, JIAN Dong-Qing. Studies on the Catalytic Action of Imidazole and Its Derivativs in the Reactlon of β-Carotene Oxidative Decomposition[J]. Chem. J. Chinese Universities, 1994, 15(9): 1361.

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Studies on the Catalytic Action of Imidazole and Its Derivativs in the Reactlon of β-Carotene Oxidative Decomposition

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