The Catalytic Behaviour of Monosubstituted Heteropoly Compounds in the Oxidation of Cyclohexene with Molecular Oxygen

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (2): 279.

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The Catalytic Behaviour of Monosubstituted Heteropoly Compounds in the Oxidation of Cyclohexene with Molecular Oxygen

QIN Du-Jie, WANG Guo-Jia, WU Yue

Department of Chemistry, Jilin University, Changchun, 130023

Received:1993-09-08 Revised:1993-12-08 Online:1994-02-24 Published:1994-02-24

Abstract

Abstract: In this paper, it was found that the transition-metal substituted heteropolymolybdates,{[(n-C₄H₉)₄N]₅PMo₁₁(Zⁿ⁺L)}(Z=Mn, Fe, Cu; L=unknown), were remarkably effective catalysts for the selective oxidation of cyclohexene with molecular oxygen under mild coriditions.Based on this, the results obtained were compared with the results for the same reaction catalyzed by related substituted heteropolytungstates and metalloporphyrins.It was found that although Mo⁶⁺ and W⁶⁺ in monosubstituted polyoxometalates could participate in the reaction,the main active center in them, is substituting transition metal.

Key words: Heteropoly compounds, Cyclohexene, Catalyzing oxidation

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QIN Du-Jie, WANG Guo-Jia, WU Yue. The Catalytic Behaviour of Monosubstituted Heteropoly Compounds in the Oxidation of Cyclohexene with Molecular Oxygen[J]. Chem. J. Chinese Universities, 1994, 15(2): 279.

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The Catalytic Behaviour of Monosubstituted Heteropoly Compounds in the Oxidation of Cyclohexene with Molecular Oxygen

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