Digital Simulation of Neutral Carrier Cation Selective Electrode Membrane Electrochemical Properties

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (11): 1602.

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Digital Simulation of Neutral Carrier Cation Selective Electrode Membrane Electrochemical Properties

WANG Ke-Min, HUO Xi-Qin, YU Ru-Qin

Department of Chemistry and Chemical Enginnering, Hunan University, Changsha, 410082

Received:1994-02-26 Revised:1994-06-14 Online:1994-11-24 Published:1994-11-24

Abstract

Abstract: Digital simulation techniques are applied to investigate the electrochemical properties of neutral carrier cation selective electrode membranes with a particular attention bening paid to three possible transport mechnisms. The effects of mobilities, concentrations, complex formation constants and hydrophilic anions on potention response are studied.The simulation results provide useful information for exploring the response mechanism of this type of electroded, explaining some experimental phenomena and designing new neutral carrier electrodes.

Key words: Neutral carrier, Ion electrode, Transport mechanism, Digital simulation

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WANG Ke-Min, HUO Xi-Qin, YU Ru-Qin . Digital Simulation of Neutral Carrier Cation Selective Electrode Membrane Electrochemical Properties[J]. Chem. J. Chinese Universities, 1994, 15(11): 1602.

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Digital Simulation of Neutral Carrier Cation Selective Electrode Membrane Electrochemical Properties

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