The Stereo-selective Synthetic Method of 2E-Unsaturated Amides

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (10): 1481.

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The Stereo-selective Synthetic Method of 2E-Unsaturated Amides

DU Jing-Xing¹, HUANG Xian²

1. Chem.Dept, Zhejiang Normal Univ.;
2. Chem.Dept.Hangzhou Univ.Hangzhou, 310028

Received:1993-11-15 Revised:1994-02-20 Online:1994-10-24 Published:1994-10-24

Abstract

Abstract: The coupling reaction of arylhalide with N, N-diethyl acrylamide under solid-liquid phase-transfer conditions with bis(benzonitrile)dichloropalladium as catalyst gave the corresponding(E)-α, β-unsaturated amides.Good yields were obtained with aryliodide as substrate.Hence this paper presents a simple stereo-selective synthetic method for 2E-unsatu-rated amides.

Key words: Palladium catalysis, Phase-transfer catalysis, Unsaturated amide, Stereo-selective synthesis

TrendMD:

DU Jing-Xing, HUANG Xian. The Stereo-selective Synthetic Method of 2E-Unsaturated Amides[J]. Chem. J. Chinese Universities, 1994, 15(10): 1481.

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The Stereo-selective Synthetic Method of 2E-Unsaturated Amides

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