Synthesis of PS Microgel with Iniferter and Star-Like Polystyrene

Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (9): 1317.

• Articles • Previous Articles Next Articles

Synthesis of PS Microgel with Iniferter and Star-Like Polystyrene

YANG Wen-Jim¹, WU Qi-Ye¹, ZHOU Li-Ling¹, LI Zeng-Ji², SHEN Jia-Cong²

1. Department of Polymer Material Engineering, Qingdao Institute of Chemical Technology, Qingdao, 266042;
2. Department of Chemistry, Jilin University

Received:1992-11-17 Revised:1993-03-29 Online:1993-09-24 Published:1993-09-24

Abstract

Abstract: By the ultrasonic oscillation dispersion method, the soluble microgel of PSwith chloromethylene was formed during copolymerization of styrene-divinylbenzene-p-chloro-methyl-styrene.When chlorine atoms in microgel were replaced by sodium N,N-diethyldithiocarbamate, the active microgel with iniferter function was obtained and it can be used to prepare the Star-Like PSinitiated by ultraviolet radiation.Iniferter functional groups remained in Star-Like polymer.

Key words: Microgel, Radical active polymerization, Star-Like polystyrene, Iniferter

TrendMD:

YANG Wen-Jim, WU Qi-Ye, ZHOU Li-Ling, LI Zeng-Ji, SHEN Jia-Cong. Synthesis of PS Microgel with Iniferter and Star-Like Polystyrene[J]. Chem. J. Chinese Universities, 1993, 14(9): 1317.

[1]	YANG Meiyue, WANG Wei, TIAN Zhiqing, LI Yingying, YUAN Zhi. Preparation of Glycyrrhetinic Acid-modified Sodium Alginate Microgel Spheres for 3D Cell Culture^† [J]. Chem. J. Chinese Universities, 2017, 38(2): 326.
[2]	TENG Xiaobo,ZHANG Chunxia,ZHANG Ying. Synthesis of the Supported Au Polystyrene/poly(acrylic acid) Composite Microspheres and Their pH Regulated Performance^† [J]. Chem. J. Chinese Universities, 2016, 37(8): 1509.
[3]	LIU Feng, WANG Xu, YE Kai-Qi, QIU Ling-Ying, SHEN Jia-Cong*. Layer-by-Layer Assembled Microgel Films Containing Silver Nanoparticles as Antimicrobial Coatings on Plastics [J]. Chem. J. Chinese Universities, 2011, 32(4): 990.
[4]	WANG Hong-Fei, TANG Chun-Yan, YANG Hao, ZHANG Li-Ming. Study on Enzyme Mimics of Molecularly Imprinted Microgels [J]. Chem. J. Chinese Universities, 2010, 31(12): 2488.
[5]	LI Xin*, ZUO Ju, LIU Ru, LI Yong. Soap-free Seeded Dispersion Polymerization Toward Monodisperse pH- and Temperature-Responsive Microgels [J]. Chem. J. Chinese Universities, 2009, 30(7): 1434.
[6]	GAI Qing-Qing^1,3, LIU Qiu-Ye¹, LI Wen-You¹, HE Xi-Wen¹, CHEN Lang-Xing¹, ZHANG Yu-Kui^1,2. Preparation of Bovine Hemoglobin-imprinted Polymer Beads via Photografting Surface-Modified Method [J]. Chem. J. Chinese Universities, 2008, 29(1): 64.
[7]	ZHOU Nan, ZHOU Ru-Ling, YAN Xiao-Hu, WANG Zhi-Liu, CHENG Rong-Shi . Single-chain Microgels from Poly( N-isopropylacrylamide) Copolymer [J]. Chem. J. Chinese Universities, 2001, 22(11): 1936.
[8]	YANG Yi, GAO Ming-Yuan, MA Rong-Jiu, BIAN Feng-Lan, SHEN Jia-Cong. Studies on Molecular Diffusion Behavior Before and After Reaction Between Pb²⁺ -Containing Microgel and H₂S in a Good Solvent [J]. Chem. J. Chinese Universities, 1994, 15(11): 1719.
[9]	LI Ze-wen, YANG Bai, YU Wei-zhong, SHEN Jia-cong, DONG Lu-lu. Analysis of Linear PS in Microgel Core/Shell Polystyrene Microparticle by TLC,GPC and TLC Scanning [J]. Chem. J. Chinese Universities, 1992, 13(7): 998.
[10]	Zhang Xi, Cha Xiao, Shen Jia-cong . Studies on Monolayer Properties of Star-Shaped Graft Copolymer Based on St-DVB Microgel/MMA [J]. Chem. J. Chinese Universities, 1991, 12(11): 1537.

Synthesis of PS Microgel with Iniferter and Star-Like Polystyrene

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 10

Recommended Articles

Metrics

Comments