Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (8): 1135.

• Articles • Previous Articles     Next Articles

Catalytic Behaviour of Pillared Materials in the Disproportionation Reaction of β-MN

SHEN Jian-Ping1, JIANG Ting-Sun1, MA Jun1, JIANG Da-Zhen1, MIN En-Ze2   

  1. 1. Department of Chemistry, Jilin University, Changchun, 130023;
    2. Research Institute of Petroleum Processing, Beijing
  • Received:1992-09-22 Revised:1993-03-03 Online:1993-08-24 Published:1993-08-24

Abstract: The catalytic reactions of β-methylnaphthalene(β-MN) were carried out over the prepared pillared materials with different pillar height, pillar density and content in the layer and pillar.The results show that β-MNis mainly converted to a-MNby isomerization over the samples.The activity and selectivity of isomerization and disproportionation have good relation to acid amount, weak acid amount and Lacid amount, respectively.Low pillar height and high pillar density are in favour of the formation of 2,6-DMN.

Key words: Pillared material, β-methylnaphthalene, Shape selectivtiy

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