Studies on the Thermodynamics of Axial Coordination Reaction of Porphinatoiron( Ⅲ )

Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (8): 1055.

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Studies on the Thermodynamics of Axial Coordination Reaction of Porphinatoiron( Ⅲ )

ZHU Zhi-ANG, RUAN Wen-Juan, JIANG Dong-Qing, CHEN Rong-Ti

Department of Chemistry, Nankai University, Tianjin, 300071

Received:1992-08-04 Revised:1992-11-30 Online:1993-08-24 Published:1993-08-24

Abstract

Abstract: Athermodynamic study is reported for the axial coordination of meso-tetrame-sitylporphinatoiron (Ⅲ) chloride (Fe(Ⅲ)TMPCl) with imidazole (Im), 2-methylimidazole (Melm), clotrimazole (CMZ ), 2-ethyl-4-methylimidazole (EMIm ) and 4'-imidazol^-1-yl-ace-tophenone(ImAPh) in dichloromethane (这里有图片19930806-1055-1.gif) (1)The equilibrium constant (β) and stoichiometric number(n) of reaction (1) were measured by spectrophotometer technique.

Key words: Meso-tetramesitylporphinatoiron( Ⅲ ) chloride, Axial coordination reaction, Equilibrium constant, Nuclear magnetic resonance spectra

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ZHU Zhi-ANG, RUAN Wen-Juan, JIANG Dong-Qing, CHEN Rong-Ti. Studies on the Thermodynamics of Axial Coordination Reaction of Porphinatoiron( Ⅲ )[J]. Chem. J. Chinese Universities, 1993, 14(8): 1055.

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Studies on the Thermodynamics of Axial Coordination Reaction of Porphinatoiron( Ⅲ )

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