Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (6): 764.
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GAO Yi-Ci, SHEN Feng-Jia, SHI Qi-Zhen
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Abstract: The title metal isocyanides were synthesized by the substitution reaction of Ugand.The reaction of CNCH2C6H5 with CrCl3(thf)3 yielded Cr(CNCH2C6H5)3Cl3.B(C6H5)4- anion was introduced into the reaction mixture only to form Cr(CNCH2C6H5)3Cl2B(C8H5)4.Two new compounds are all stable in air and unstable in chloroform, dichloromethane, acetone and other organic solvents.Their IRspectra and thermal stability have been investigated.
Key words: Cr(CNCH2C6H5)3Cl3, Cr(CNCH2CeH5)3Cl2B(C6Hs)4·H2O, Metal isocyanide complex
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GAO Yi-Ci, SHEN Feng-Jia, SHI Qi-Zhen . Studies on the Synthesis and Property of Cr(CNCH2C6H5)3Cl3 and Cr(CNCH2C·H5),Cl2B(C6H5)4 H2O[J]. Chem. J. Chinese Universities, 1993, 14(6): 764.
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http://www.cjcu.jlu.edu.cn/EN/Y1993/V14/I6/764
