Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (5): 646.

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The Syntheses and Characterization of Zirconium (Ⅳ),Tin(Ⅳ) Titanium (Ⅳ) Complexes with Aeylhydrazones and Thioacylhydrazones

WANG Ji-Tao, GAO Sheng-Hua, LIAO Xiang-Min, LIU Feng-Quan   

  1. Department of Chemistry, Nankai Uriversity, Tianjin, 300071
  • Received:1992-07-06 Revised:1993-03-01 Online:1993-05-24 Published:1993-05-24

Abstract: Acyl- and thioacvlhvdrazones formed by condensation of salicylaidehyde or 2-hydroxy- 1 -naphthaldehyde with acylhydrazines or methanediacylhydrazines can react with Cp2ZrCl2, Ph2SnCl2, TiCl4, and SnCl4 to give 9 novel complexes.The products were characterized by elementary analysis, IRand 1H NMR.The complex of Ph2SnCl2 with methanediacyl hydrazone was structurally characterized by X-ray diffraction.

Key words: Acyl hvdrazone, Zirconocene dichloride, Diphenyltin dichloride.Tin tetrachloride, Tha-nium tetrachloride

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