Studies on the New Complexing Adsorbents (Ⅲ) --Synthesis and Characterization of Complexing Adsorbents Containing Polyamine and Nickel (Ⅱ) as Template

Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (11): 1619.

• Articles • Previous Articles Next Articles

Studies on the New Complexing Adsorbents (Ⅲ) --Synthesis and Characterization of Complexing Adsorbents Containing Polyamine and Nickel (Ⅱ) as Template

HE Bing-Lin, WANG Bu-Sen, DING Ze-Ren, LI Wen-Lan, GUO Zhen-Liang

Institute of Polymer Chemistry, Nankai University, Tianjin, 300071

Received:1993-01-12 Revised:1993-05-04 Online:1993-11-24 Published:1993-11-24

Abstract

Abstract: Aseries of complexing polymeric adsorbents made of crosslinked polyamine and nickel (Ⅱ) acting as template ion were synthesized through the polycondensation of epichlorohydrin and tetraethylenepentamine in oil disperse system.The characterization of the sorption for Cu (Ⅱ),Ni(Ⅱ),Zn(Ⅱ) and Co(Ⅱ) metal ions was studied.The results show that the sorption capacities of the kinds of complexing adsorbents for Cu (Ⅱ), Ni (Ⅱ), Zn (Ⅱ), Co (Ⅱ) are 239.60, 231.30, 131.83, 81.23 mg/g resin, respectively.The sorption capacities are in following sequence: Cu(Ⅱ)≈Ni(Ⅱ)>Zn(Ⅱ)>Co(Ⅱ).

Key words: Complexing adsorbent, Template polymerization, Ligand complex

TrendMD:

HE Bing-Lin, WANG Bu-Sen, DING Ze-Ren, LI Wen-Lan, GUO Zhen-Liang . Studies on the New Complexing Adsorbents (Ⅲ) --Synthesis and Characterization of Complexing Adsorbents Containing Polyamine and Nickel (Ⅱ) as Template[J]. Chem. J. Chinese Universities, 1993, 14(11): 1619.

[1]	XIAN Chun-Ying, ZHU Long-Guan, YU Qing-Sen . Syntheses, Crystal Structure and Spectra of Mixed Ligand Complex of Lanthanide [Ln(BA)₂(NO₃)(phen)]₂ [J]. Chem. J. Chinese Universities, 1999, 20(10): 1504.
[2]	YAN Chun-Hua, ZHANG Ya-Wen, JIA Jian-Tao, LI Biao-Guo, HUANG Chun-Hui. Studies on Rare Earth Complexes of Quaternary Ammonium Salt(Ⅶ)──Synthesis,Characterization and Structure of Tetrabutylammonium Dinitrato Tetraisothiocyanato Erbiumate [J]. Chem. J. Chinese Universities, 1996, 17(1): 1.
[3]	ZHANG Ya-Wen, YAN Chun-Hua, LI Biao-Guo, HUANG Chun-Hui, XU Guang-Xian, MA Zhe-Sheng, TANG Chun-Hong. Studies on Rare Earth Complexes of Quaternary Ammonium Salt(Ⅵ)--Synthesis,Characterization and Crystal Structure of Tetrabutylammonium Tetranitrato Diisothiocyanato Neodymate [J]. Chem. J. Chinese Universities, 1995, 16(7): 997.
[4]	LE Xue-Yi, WU Fu-Hai, SONG Fen-Yun, JI Liang-Nian. Studies on Stability of Ternary Mixed-ligand Complexes of M (Ⅱ)(ATP)^2-and Nucleic Acid Bases (Adenine and Cytosine) [J]. Chem. J. Chinese Universities, 1995, 16(10): 1500.
[5]	ZHANG Wei-Ling, ZHENG Li-Min, LEI Li-Xu, XIN Xin-Quan. Studies on the Solid State Reactions of Coordination Compounds(LXVII)─The Synthesis of Mixed Ligand Complexes in Solid State [J]. Chem. J. Chinese Universities, 1994, 15(10): 1443.
[6]	HE Bing-Lin, WANG Bu-Sen, LI Wen-Lan, DING Ze-Ren, GUO Zhen-Liang. Studies on the New Complexing Adsorbents(Ⅳ)──The Memorial Properties of Complexing Adsorbents Containing Polyethylene Polyamine and Copper(Ⅱ) or Nickel(Ⅱ) used as Template Ions [J]. Chem. J. Chinese Universities, 1994, 15(1): 132.
[7]	WANG Bu-Sen, DING Ze-Ren, LI Wen-Lan, GUO Zhen-Liang, HE Bing-Lin . Studies on the New Complexing Adsorbents (Ⅱ)——Synthesis and Characterization of Complexing Adsorbents Containing Polyamine and Cupric(Ⅱ) as Template [J]. Chem. J. Chinese Universities, 1993, 14(4): 582.
[8]	WANG Xiao-Ling, YAO Ke-Min . Studies on Novel Mixed Ligand Complexes of Rare Earth Acetylacetonates and Dibenzo-18-Crown-6 by Using Reflectance Spectrophotometry [J]. Chem. J. Chinese Universities, 1993, 14(1): 1.
[9]	Kang Jingwan, Zhu Zhongping, Lu Xiaoquan, Chen Guangde, Oao Jinzhang, Bai Guangbi . A Polarographic Study of the Formation of Ternary Mixed-Ligand Complex——Determination of the Stability Constant of Cd( Ⅱ )-Bipy-Gly Ternary System [J]. Chem. J. Chinese Universities, 1990, 11(8): 813.
[10]	Huang Chunhui, Wang Kezhi, Xu Zheahua, Xu Guangxian, Han Yuzhen, Shi Nicheng. Synthesis, Characterization and Crystal Structure of Di-(1-Phenyl-3-Methyl-4-Trifluoroacetylpyrazolone-5) Di-(Ethanol) Cobalt (Ⅱ) [J]. Chem. J. Chinese Universities, 1989, 10(2): 129.
[11]	Cao Junkui, Yoshio Okamoto, Shiro Honda, Koichi Hatada. Synthesis of Narrow Distribution Polystyrene in RLi-Ligand Complex Systems [J]. Chem. J. Chinese Universities, 1989, 10(12): 1246.
[12]	Gao Zhisheng . A Theoretical Study of Optimum Ligand Concentration Ratio in a Mixed Ligand Complex [J]. Chem. J. Chinese Universities, 1988, 9(5): 513.

Studies on the New Complexing Adsorbents (Ⅲ) --Synthesis and Characterization of Complexing Adsorbents Containing Polyamine and Nickel (Ⅱ) as Template

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 12

Recommended Articles

Metrics

Comments