Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (1): 54.
• Articles • Previous Articles Next Articles
LIU Yun-Shan, JIANG Tao, BEI Mei-Zhi
Received:
Revised:
Online:
Published:
Abstract: The zero-valent Sm on graphite has been prepared by the reduction of anhydrous SnCl3 with potassium graphite (C8K) in refluxing THFunder a purified nitrogen atmosphere.It showed a greater activity than commercial block Sm metal, and reacted with PhCOCl smoothly at r.t.to give the benzil 1, benzoin 2 and stibenediol dibenzoate 3.Compound 3 is the major product and the cis-form of 3 is the dominant among its geometrical isomers.
Key words: Zero-valent Sm, C8K, PhCOCl
TrendMD:
LIU Yun-Shan, JIANG Tao, BEI Mei-Zhi . Studies on the Application of Lanthanoid Metals to Organic Reactions (Ⅳ)——The Reaction of Sm(0) on Graphite with PhCOCl[J]. Chem. J. Chinese Universities, 1993, 14(1): 54.
0 / / Recommend
Add to citation manager EndNote|Ris|BibTeX
URL: http://www.cjcu.jlu.edu.cn/EN/
http://www.cjcu.jlu.edu.cn/EN/Y1993/V14/I1/54
