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Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (1): 119.

• Articles • Previous Articles     Next Articles

Studies of the Ligand and Sodium Complex of Polysiloxanes with Liquid-Crystal Crown-Ether-Containing Side Chains

ZHANG Shu-Yuan, ZHAO Yu-Bin   

  1. Department of Chemistry, Zhengzou Universty, Zhengzhou, 450052
  • Received:1992-01-29 Revised:1992-04-10 Online:1993-01-24 Published:1993-01-24

Abstract: Anew ligand and sodium complex of poiysiioxanes with liquid-crystal crown-ether-containing side chain woe synthesized by the hydrosilyiation reaction using mesogenic monomer, 4-(allyloxy)-4' -(4' -carboxybenzo-15-crown-5)-α,to-diphenoxybutane and poly(methylsiloxane) with Cp2PtCl2 as catalyst.The liquid crystalline behavior of the monomer, liganci and complex was studied by DSCand polarized optical microscopy.It was found that they are thermotropic.

Key words: Side chain liquid crystal polvsiloxanes, Crown ether.Sodium complex

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