Electronic Structures and Nonlinear Third-Order Optical Properties of Ni-Porphyrin

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (9): 1238.

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Electronic Structures and Nonlinear Third-Order Optical Properties of Ni-Porphyrin

FENG Ji-Kang, GAO Xu-Ling, SUN Jia-Zhong

Department of Chemistry, Institute of Theoretical Chemistry, Jilin University, Changchun, 130023

Received:1991-09-06 Online:1992-09-24 Published:1992-09-24

Abstract

Abstract: The electronic structure UVspectrum and nonlinear third-order optical susceptibility γof Ni-porphyrin were studied.It can be concluded that in this compound the contribution of Ni²⁺ ion to γis very littles the contribution of porphyrin ring to γ is the dominant one and the nonlinear third-order optical susceptibility will increase exponentially with the increase of the number of conjugated bonds of ligands in the complex.

Key words: Ni-porphyrin, UV spectrum, Nonlinear third-order optical susceptibility

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FENG Ji-Kang, GAO Xu-Ling, SUN Jia-Zhong . Electronic Structures and Nonlinear Third-Order Optical Properties of Ni-Porphyrin[J]. Chem. J. Chinese Universities, 1992, 13(9): 1238.

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Electronic Structures and Nonlinear Third-Order Optical Properties of Ni-Porphyrin

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