Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (6): 857.

• Articles • Previous Articles     Next Articles

Structure and Properties of Multicomponent Metal-Containing Transparent Resin

JIA Chun-xiang, YANG Bai, LIN De-hou, LI Ying-jun, SHEN Jia-cong   

  1. Department of Chemistry, Jilin University, Changchun, 130023
  • Received:1991-07-08 Online:1992-06-24 Published:1992-06-24

Abstract: In this paper, transparent resin——copolymer of styrene, bisvinyl poly (ether-sul-fone)s macromonomer(PES-3-MA), Pb(MA)2, Ba (CA)2 was synthesized, and the relation between structure and properties of the multicomponent transparent resin was studied.The experimental results indicate that with the increases of PES-3-MAor Pb(MA)2 ratio, the density of the resin will increase, the linear expansion coefficient a will decrease to 50~70×10-6-1, Tg arise to 140℃.It was obtained that D204p(PES-3-MA)=1.33, D204p[Pb(MA)2]=2.10.This is consistent with the calculated value.Studies by FTIRshow that if one wants pendant vinyl bond to react completely, high temperature heat treatment is needed.

Key words: Multicomponent metal-containing polymer, Transparent resin, Structure and properties

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