Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (6): 857.
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JIA Chun-xiang, YANG Bai, LIN De-hou, LI Ying-jun, SHEN Jia-cong
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Abstract: In this paper, transparent resin——copolymer of styrene, bisvinyl poly (ether-sul-fone)s macromonomer(PES-3-MA), Pb(MA)2, Ba (CA)2 was synthesized, and the relation between structure and properties of the multicomponent transparent resin was studied.The experimental results indicate that with the increases of PES-3-MAor Pb(MA)2 ratio, the density of the resin will increase, the linear expansion coefficient a will decrease to 50~70×10-6℃-1, Tg arise to 140℃.It was obtained that D204p(PES-3-MA)=1.33, D204p[Pb(MA)2]=2.10.This is consistent with the calculated value.Studies by FTIRshow that if one wants pendant vinyl bond to react completely, high temperature heat treatment is needed.
Key words: Multicomponent metal-containing polymer, Transparent resin, Structure and properties
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JIA Chun-xiang, YANG Bai, LIN De-hou, LI Ying-jun, SHEN Jia-cong . Structure and Properties of Multicomponent Metal-Containing Transparent Resin[J]. Chem. J. Chinese Universities, 1992, 13(6): 857.
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http://www.cjcu.jlu.edu.cn/EN/Y1992/V13/I6/857