Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (5): 686.

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Infrared and Raman Spectra of [Pd2Cl2(PPh3)4]·B12H12

HE Ji-ping1, SUN Li1, CHEN Xin-lan2, ZHANG Lun2   

  1. 1. Centre of Research and Analysis of Materials, Wuhan University of Technology, Wuhan, 430070;
    2. Department of Chemistry, Wuhan University, Wuhan
  • Received:1991-04-15 Online:1992-05-24 Published:1992-05-24

Abstract: The IRand Raman spectra of PdCl2(PPh3)2 and [Pd2Cl2(PPh3)4]·B12H12 were determined.Based on the observed Raman frequencies, the Pd—Cl stretching vibration can be assigned at 311-312 cm-1(one band) for [Pd2Cl2(PPh3)4]·Bi2H12. Similarly, the Pd-Pstretching bands are assigned at 153~156 cm-1 and at 147 cm-1 for [Pd2Cl2(PPh3)4] ·B12H12.

Key words: Raman spectra, Infrared spectra, Stretching vibration, [Pd2Cl2(PPh3)4]·B12H12

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