Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (5): 576.
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DUAN Chun-ying, XIA Xu-bing, ZHU Long-gen, YOU Jing-jing, CAO Hong
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Abstract: Polynuclear complexes containing Nand Satoms [M(Fc-C(CH3)= NN=CSSR)2,R=—CH3, —CH2C6H5, M=Co2+, Ni2+, Cu2+, Zn2+, Cd2+] were synthesized.It was found that the coordination compounds could quench *Ru(bpy)32+ with high efficiency.The Stern-Volmer plot is linear and yields the bi-molecular quenching rate constants for these compounds.The quenching luminescence of the *Ru(bpy)32+ proceeded through the electron transfer mechanism.
Key words: Polynuclear complexes, Quench process, Electron transter mechanism
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DUAN Chun-ying, XIA Xu-bing, ZHU Long-gen, YOU Jing-jing, CAO Hong. Synthesis of Polynuclear Fc-M-Fc Complexes Containing N and S Atoms and Quenching the Luminescence of Ru(bpy)32+[J]. Chem. J. Chinese Universities, 1992, 13(5): 576.
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http://www.cjcu.jlu.edu.cn/EN/Y1992/V13/I5/576