The Determination of Stability Constants of Complexes of Zn(Ⅱ) and Cd(Ⅱ) with Amino-Acids, Dipeptides and Tripeptides by Micro-pH-Potentiometric Titration

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (3): 322.

• Articles • Previous Articles Next Articles

The Determination of Stability Constants of Complexes of Zn(Ⅱ) and Cd(Ⅱ) with Amino-Acids, Dipeptides and Tripeptides by Micro-pH-Potentiometric Titration

LU Ai-ru¹, Pettit L. D.², Gregor J. E.²

1. Department of Chemistry Northwest Normal University, Lanzhou, 730070;
2. School of Chemistry, University of Leeds, Leeds, England

Received:1991-02-05 Online:1992-03-24 Published:1992-03-24

Abstract

Abstract: A potentiometric study on the complexes of His, Gly-His, Ala-His, Gly-Gly and Gly-Gly-Gly with Zn(Ⅱ), Cd(Ⅱ) is reported and small scale (piston buretle or microsyrine) potentiometric titrations were carried out to determine the stability constants of complexes at 25 ℃ and I = 0.10 mol/L (KNO₃) conditions.The data treatment were performed with the computer program TITRE and SUPERQUAD on a BBCmicro-computer.The stisfactory results has been obtained by using this method.

Key words: Zinc(Ⅱ), Cadmium(Ⅱ), Amino-acid, Dipeptide, Tripeptide, Micro-pH-potentio-metric titration

TrendMD:

LU Ai-ru, Pettit L. D., Gregor J. E.. The Determination of Stability Constants of Complexes of Zn(Ⅱ) and Cd(Ⅱ) with Amino-Acids, Dipeptides and Tripeptides by Micro-pH-Potentiometric Titration[J]. Chem. J. Chinese Universities, 1992, 13(3): 322.

[1]	YIN Juxin, LI Zuhong, MU Ying, LÜ Shaowu, LUO Guimin. Tripeptide Containing Selenium with Glutathione Peroxidase Activity^† [J]. Chem. J. Chinese Universities, 2016, 37(7): 1302.
[2]	WU Ruofei, CHU Yanqiu, XU Chongsheng, LIU Zhipan, DING Chuanfan. Fragmentation Reaction of Complexes of Alkali Metal Cations with Tripeptides in Gas Phase^† [J]. Chem. J. Chinese Universities, 2016, 37(12): 2150.
[3]	GUO Kai, ZHANG Heng, SUN Jichao, YUAN Shiling, LIU Chengbu. Molecular Dynamics Simulation on Self-Assembly of Fmoc-FF Dipeptide^† [J]. Chem. J. Chinese Universities, 2015, 36(11): 2171.
[4]	GUO Zhi-Fo, YAN Hao, LI Zhi-Fen, LU Zhong-Lin*. Synthesis of New [12]aneN3 Compounds and Their Catalytic Cleavage of Phosphodiester [J]. Chem. J. Chinese Universities, 2011, 32(9): 2128.
[5]	CHEN Nian-You*, ZHAO Sheng-Fang, DONG Jia-Qing, TIAN You-Ping, LI Zao-Ying. Microwave Synthesis and Electron Transfer Properties of a Series of New Porphyrin-anthraquinone Hybrids with Dipeptide Link and Their Metal Complexes [J]. Chem. J. Chinese Universities, 2011, 32(7): 1466.
[6]	WANG Guang-Rong, ZENG He-Ping*. Synthesis, Electroluminescent Properties of 2-[2-(9-Aryl-9H-carbazol-3-yl)vinyl]-8-hydroxyquinoline and Their Each Zinc(Ⅱ) Complexes [J]. Chem. J. Chinese Universities, 2009, 30(6): 1140.
[7]	YANG Ying-Qun¹, LI Chang-Hong², LI Wei¹*, LI Dong-Ping³, KUANG Yun-Fei¹. Hydrothermal Synthesis, Crystal Structure, Luminescence and Electrochemical Properties of Trinuclear Zinc(Ⅱ) Complex Zn₃(phen)₂(2,4-DAA)₆ [J]. Chem. J. Chinese Universities, 2008, 29(3): 449.
[8]	ZHOU Yuan^1,3,4, MEI Hu^2,3, YANG Li³, ZHOU Peng², YANG Shan-Bin^3,4, LI Zhi-Liang^2,3,4*. Amino Acid Structural Descriptions Based on Random Sampling of Pseudo Atomic Probe and Its QSAR Study [J]. Chem. J. Chinese Universities, 2007, 28(7): 1263.
[9]	SU Tan¹, ZHU Dong-Xia^1,2, QIU Yong-Qing²*, CHEN Hui², WANG Yue^1,2. Electronic Structures and Second-order Nonlinear Optical Properties of Zinc(Ⅱ) Complexes with Bis(salicylaldiminatio) Schiff Bases and Pyridine Ligands [J]. Chem. J. Chinese Universities, 2007, 28(7): 1361.
[10]	WANG Hua, Zhao-Mi-Feng, Li-Gang, Huang-Yi-Bing, Hou-Rui-Zhen, Ceng-Hong-Bin, Xu-Li, Zhang-Xua-Zhong. Chemical Synthesis and Esterification of a Precursor Dipeptide of RGD as a Site for Cell Adhesion [J]. Chem. J. Chinese Universities, 2006, 27(2): 240.
[11]	HE Jun, MA Yuan, ZHAO Yu-Fen. Cleavage of λDNA by Seryl-histidine Planted Peptide Dendrimer [J]. Chem. J. Chinese Universities, 2006, 27(10): 1891.
[12]	ZHANG Hui-Juan, FENG Juan, SUN Zhao-Yong, AI Xi-Cheng, ZHANG Jian-Ping, ZHANG Xing-Kang, YU Zhong-Heng, HAN Shi-Tian, LIU Yan-Qin, WU Yin-Su . Effect of Different Chlorine Substituted Positions on the Photophysical Property of Zinc(Ⅱ) Tetraphenylporphyrin-tyrosine [J]. Chem. J. Chinese Universities, 2003, 24(11): 2069.
[13]	LIU Xue-Jun, CHEN Ru-Yu, YANG Yuan-Yuan. Synthesis and Anticancer Activities of Novel5-Fluorouracil-1-yl Phosphonotripeptides [J]. Chem. J. Chinese Universities, 2002, 23(7): 1299.
[14]	CHEN Shi, LU Tong-Bu, FENG Xiao-Long, LI Yan-Wu, MAO Zong-Wan, JI Liang-Nian . Synthesis, Structure and Stability of Binuclear Metal Complexes with Macrocyclic Ligand [J]. Chem. J. Chinese Universities, 2002, 23(6): 1004.
[15]	KANG Li-Tao, SHI Guo-Shun, SHEN Xiao-Liang, MA Li-Dun, XU Xiang-Fa. The Synthesis of Zinc(Ⅱ)-L-Cysteine and Its Structural Characterization with X-ray Powder Diffraction [J]. Chem. J. Chinese Universities, 2002, 23(3): 475.

The Determination of Stability Constants of Complexes of Zn(Ⅱ) and Cd(Ⅱ) with Amino-Acids, Dipeptides and Tripeptides by Micro-pH-Potentiometric Titration

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments