Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (3): 284.
• Articles • Previous Articles Next Articles
CHEN Jing-tang, LIAO Dai-zheng, ZHANG Ruo-hua, CHEN Hui, LU Jian-yi
Received:
Online:
Published:
Abstract: Two dicopper complexes containing different exogenous bridges, Cu2(pfhmp)OH·2H2Oand Cu2(pfhmp)N3·H2O, were synthesized, where pfhmp3- denotes dehydrogen anion of N,N-diisonicotinoyl-2-hydroxy-4-methylisophthalaldehyde dihydrozone.Based on elemental analysis, IRand molar conductance, the complexes are proposed to have hetergeneous bridged structures and enolic configuration.The determination of variable-temperature magnetic susceptibility indicates that the variation of exogenous bridge obviously changes magnetic exchange interaction between two Cu(Ⅱ) ions.
Key words: Binuclear copper complex, Hetergeneous bridge, Enolic configuration, Magnetic exchange interction
TrendMD:
CHEN Jing-tang, LIAO Dai-zheng, ZHANG Ruo-hua, CHEN Hui, LU Jian-yi . Studies on the Synthesis and Magnetic Exchange Interaction of Novel Heterogeneous Bridged Enolic Dicopper Complexes[J]. Chem. J. Chinese Universities, 1992, 13(3): 284.
0 / / Recommend
Add to citation manager EndNote|Ris|BibTeX
URL: http://www.cjcu.jlu.edu.cn/EN/
http://www.cjcu.jlu.edu.cn/EN/Y1992/V13/I3/284
