Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (3): 281.

• Articles •     Next Articles

Phase Transformation of Molecular Sieve VPI-5 into AlPO4-8 and the Relationship Between Both Frameworks

XU Yi-hua, YAO Shang-qing, LIU Xin-sheng, PANG Wen-qin   

  1. Institute of Synthetic and catalytic Chemistry, Jilin University, Changchun, 130023
  • Received:1991-03-09 Online:1992-03-24 Published:1992-03-24

Abstract: The aluminophosphate molecular sieve VPI-5 has been received much attention as a new structure containing super-large open pores with 18 tetrahedral atoms.During the propcess of dehydration and desorption of water molecules in the channeles, the framework structure can be converted into AlPO4-8, which contains 14-membered ring open pores.The process of phase transformation was studied and the mechanism about the transformation is discussed.

Key words: VPI-5, AlPO4-8, Aluminophosphate molecular sieve

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