Infrared and Raman Spectra of Tetra(p-nitrophenyl) Porphyrin and Its Transition Metal Complexes

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (11): 1432.

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Infrared and Raman Spectra of Tetra(p-nitrophenyl) Porphyrin and Its Transition Metal Complexes

SHI Tong-Shun¹, ZHENG Guo-Dong¹, ZHOU Jian-Gang¹, LI Dong-Mei¹, CAO Xi-Zhang¹, DONG Qing-Rong²

1. Department of Chemistry, Jilin University, Changchun, 130023;
2. Broadcast Television University of Jilin Province, Changchun

Received:1991-12-12 Revised:1992-04-20 Online:1992-11-24 Published:1992-11-24

Abstract

Abstract: The Infrared spectra(220-3500 cm^-1)and Raman spectra(100-1700 cm^-1)of te-tra(p-nitrophenyl)porphyrin and its Cr(Ⅲ),Mn(Ⅲ),Fe(Ⅲ),Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ)and Zn(Ⅱ)complexes were measured and investigated respectively.The band at 3321 cm^-1 and 988 cm^-1 belonging to N-Hvibrations of pyrrole disappears when the complex formed.The metal sensitive bands were found at ～1600,～1582,～1547,～1284,～1190,～355 and ～245 cm^-1.The bands at ³55 and ²45 cm^-1 of the complexes decrease in wave number in the order of Ni(Ⅱ)>Co(Ⅱ)>Cu(Ⅱ)>Zn(Ⅱ).The bands at ～3110,～1600,～1520,～1350,～850 and ～825 cm^-1 resulted from p-nitrobenzene of the porphyrin.

Key words: Porphyrin complexes, Infrared spectra, Raman spectra

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SHI Tong-Shun, ZHENG Guo-Dong, ZHOU Jian-Gang, LI Dong-Mei, CAO Xi-Zhang, DONG Qing-Rong. Infrared and Raman Spectra of Tetra(p-nitrophenyl) Porphyrin and Its Transition Metal Complexes[J]. Chem. J. Chinese Universities, 1992, 13(11): 1432.

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Infrared and Raman Spectra of Tetra(p-nitrophenyl) Porphyrin and Its Transition Metal Complexes

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