Synthesis and Axial Coordination Reduction of Tetrakis(4-nitrophenyl) porphyrin Manganese (Ⅲ) Chloride

Abstract

Abstract: A kind of porphyrinmaganese (Ⅲ) complex, meso-tetra (4-nitrophenyl) porphyrinman-ganese(Ⅲ) chloride was synthesized The adducts of this porphyrinmanganese (Ⅲ) complex with di atomic molecules such as CO, NOand some organic bases are studied by means of the spectroscopic method. The experimental results show that electron-attracting substituents such as nitro(NO₂) on the porphyrin cycle can make the reduction process from Mn(Ⅲ) to Mn(Ⅱ) operate easily. In the presence of trace methanol, NO can reduce this porphyrinmnanganese(Ⅲ) complex.

Key words: Porphyrin manganese(Ⅲ), Coordination reductin, Syntheses

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Shi Tong-shun, Liu Ben-cai, Wang Qing-min, Ma Tao, Cao Xi-zhang . Synthesis and Axial Coordination Reduction of Tetrakis(4-nitrophenyl) porphyrin Manganese (Ⅲ) Chloride[J]. Chem. J. Chinese Universities, 1991, 12(8): 995.

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Synthesis and Axial Coordination Reduction of Tetrakis(4-nitrophenyl) porphyrin Manganese (Ⅲ) Chloride

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