Chem. J. Chinese Universities ›› 1991, Vol. 12 ›› Issue (7): 921.

• Articles • Previous Articles     Next Articles

Studies on Organoarsenic Compounds (XⅧ)--Effects of Solvents on the Reaction Products of the o-Fluorobenzyltri-phenylarsonium Bromide with Aromatic Aldehydes

Zeng Wu-Zong, Tao Wen-tian   

  1. Department of Chemistry, Wuhan University, Wuhan, 430072
  • Received:1990-04-22 Online:1991-07-24 Published:1991-07-24

Abstract: This paper presents the reaction of arsonium salts (1,2) with aromatic aldehydes in the two phase system of C6H6(CH2Cl2)-50% NaOH(aq.) at room temperature to afford frons-olefinic derivatives (3a-i), and the yields were 86%-94%. We also found that the solvent effects exist in the phase transfer reaction between (2) with the aromatic aldehydes.

Key words: Solvent effects, Arsonium salts, Phase transfer

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