Abstract: A new kind of catalyst, 1,1-bis(benzylethio)ferrocene platinum and rhodium complexes, for the hydrosilylation were synthesized and their catalytic behaviour for the hydrosilylation of olefins, including decene, dodencene, allyl benzene, phenyl allyl ether and allyl glycidyl ether, with triethoxysilane was studied under the atmosphere pressure and at the temperature between 70～100℃.

Key words: Ferrocenyl disulfide, Platinum-sulfide complex, Rhodium-sulfide complex, Hydrosilylation catalyst