CJCU

Chem. J. Chinese Universities ›› 1991, Vol. 12 ›› Issue (6): 795.

• Articles • Previous Articles     Next Articles

A Theoretical Study of Electric Dipole Transition Intensity of the TbP5O14Compounds Emission Spectrum

Huang Ai-ping1, Li Bo-fu2, Sun Jia-zhong2   

  1. 1. Dept. of Phys., South China Normal Univ.;
    2. Inst. of Theoretical Chem., Jilin Univ., Changchun, 130021
  • Received:1989-10-19 Online:1991-06-24 Published:1991-06-24

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Abstract: Taking account of the perturbation of an odd crystal field, we derive an oscillator intensity formula describing electric dipole transition of rare earth compound spectra, and extend the famous JOtheory by our formula. Acalculation is performed for emission spectrum intensities of 5D4→7FJ(J=1,2,6) of TbP5O14 crystal. The results agree basically with the experimenttal results.

Key words: Odd crystal field, Oscillator intensity) Electric dipole transition

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