Preparation and Characterization of LB Film of Ni(Ⅱ) Complex of 5-(p-hydroxyphenyl)-10,15,20-tris(p-methoxyphenyl)porphyrin

Abstract

Abstract: The Ni(n) complex of 5-(p-hydroxyphenyl)-10,15,20-tris(p-methoxyphenyl)porphyrin was prepared. The composition and structure of the complex were identified by elemental analysis, UVand 1R spectrometry. The thermostability of the complex was determined with thermogravimetry. The procedure of deposition and influence of pHon the formation of the films were also studied. The uniformity of the films was varified by angle resolved XPS spectra. The difference of spectra(UV-Vis) of molecules in LBfilms and in the solution was indicated. The crosswise resistance of monolayer films was determined.

Key words: 5-(p-hydroxyphenyl)-10,15,20-tris(p-methoxyphenyl)porphyrin, Nickel Complex of porphyrin, LB films

TrendMD:

Yang Kong-zhang, Liu Yan, Feng Xu-sheng, Dong Yu-lin . Preparation and Characterization of LB Film of Ni(Ⅱ) Complex of 5-(p-hydroxyphenyl)-10,15,20-tris(p-methoxyphenyl)porphyrin[J]. Chem. J. Chinese Universities, 1991, 12(3): 400.

[1]	WANG Yi-Bing^1,2, LU Fei^1,2, WEI Ping-Hui¹, XI Shi-Quan¹, WANG Hai-Shui^1*. Preparation and Characterization of Langmuir-Blodgett Film of Charge-transfer Complex of 2-Octadecyl-7,7,8,8-tetracyanoquino-dimethane and 3,3′,5,5′-Tetramethylbenzidine [J]. Chem. J. Chinese Universities, 2006, 27(5): 935.
[2]	LIU Shi-Zhong, ZHANG Zhen-Wen, WANG Jun, DU Zu-Liang, DAI Shu-Xi. Studies on the Preparation, Structure and Properties of LB films of 12-Tungstomolybdophosphheteropolyacid with Dimethyldioctadecylammonium [J]. Chem. J. Chinese Universities, 2002, 23(1): 27.
[3]	BEN Teng, CHEN Chun-Hai, SUN Hui, CAO Hui, YU Kun-Qian, LIU Xin-Cai, WANG Xing, QIU He, WU Zhong-Wen, ZHANG Wan-Jin, XIA Qing-Tao, WEI Yen. Structures of 2D Ordered Monolayer of Rigid Cyclic Oligomer [J]. Chem. J. Chinese Universities, 2001, 22(8): 1428.
[4]	LÜ Wei-Xing, GUO Wei-Hua, FANG Kun, HE Ping-Sheng . Monolayer and LB Films of Ru(dpphen)₃^²⁺ and Arachidic Acid Mixture [J]. Chem. J. Chinese Universities, 2001, 22(4): 691.
[5]	HE Xue-Zhong, ZHOU Ya-Lin, WANG Ling-Xuang, LI Tian-Kai, ZHANG Man-Hua, SHEN Tao. Studies on Structure of TC₁₆PyP(4)/AnQ LB Films [J]. Chem. J. Chinese Universities, 2000, 21(12): 1919.
[6]	ZHANG Wei-Feng, GUO Hong, MA Guo-Hong, HUANG Ya-Bin, DU Zu-Liang . Photo-electric Properties of Ordered Films of Polyvinylcarbazole and Arachidic Acid [J]. Chem. J. Chinese Universities, 1998, 19(4): 591.
[7]	LI Hong-Bin, ZHANG Li, WANG Zhi-Qiang, ZHANG Xi, SHEN Jia-Cong, YANG Yan-Qiang, FEI Haou-Sheng. Reversed Duckweed Polymeric LB Film Containing Azo Chromophores and Its Properties of Reversible Optical Storage [J]. Chem. J. Chinese Universities, 1997, 18(2): 323.
[8]	YE Yu-Han, XIAO Yu-Fang. Studies on Characteristics and Conductivity of 1,3,6,11,13,18,28,31-Octabromofullerene-C₆₀LB Films [J]. Chem. J. Chinese Universities, 1996, 17(2): 300.
[9]	PENG Xiao-gang, LI Lin-song, ZHANG Yan, BAI Yu-bai, LI Tie-jin, YU Zhan-jun. Thermal Stability and Thermal Behavior of Nanoparticle a-Fe₂O₃-stearate Alternating Langmuir-BIodgett Multilayer [J]. Chem. J. Chinese Universities, 1995, 16(S1): 41.
[10]	GAO Yu-Zhi, ZHU Tao, TANG Ming, CAI Sheng-Min, LIU Zhong-Fan. Structural Investigation of Langmuir-Blodgett Films on Self-Assembly Modified Au Substrates [J]. Chem. J. Chinese Universities, 1995, 16(S1): 120.
[11]	REN Yan-zhi, CHEN Si-guang, CHAI Xiang-dong, CAO Yun-wei, YANG Wen-sheng JIANG Yue-shun, LI Tie-jin, ZHAO Bing, Lehn Jean-Marie. Alternating Langmuir-Blodgett Films with Interlayer Molecular Recognition [J]. Chem. J. Chinese Universities, 1995, 16(S1): 134.
[12]	Zhang L., ZHU M., LIU Z.X., SHEN J.C., BAI Y.B., LI T.J., WEI C., SONG W.X.. Investigation of the Electrical and the Dielectric Properties of Various LB Films [J]. Chem. J. Chinese Universities, 1995, 16(S1): 167.
[13]	CHEN Hai-Yan, PENG Xiao-Gang, YU Lian-Xiang, ZHOU Yong-Liang, JIANG Yue-Shun, LI Tie-Jin, XU Yue, GAO Zhong-Min, WEI Quan. Preparation and Structure Characterization of Pure Y-Type LB Films of Lead Stearate [J]. Chem. J. Chinese Universities, 1994, 15(1): 20.
[14]	WEN Ke, LI Cao-Hui, CAO Xi-Zhang, GU Chang-Zhi, ZHANG Tong, SUN Liang-Yan . Synthesis of Cobalt Porphyrin Containing Aliphatic Chains, and Its LB Films and Gas Sensitivity [J]. Chem. J. Chinese Universities, 1993, 14(2): 147.
[15]	LUO Yi, WU Xuan-Jie, CHEN Zhang-Ping, JIANG Zhong-Xing. The Synthesis of A Novel Amphiphilic Porphyrin and the Properties of LB Films [J]. Chem. J. Chinese Universities, 1992, 13(8): 1092.

Preparation and Characterization of LB Film of Ni(Ⅱ) Complex of 5-(p-hydroxyphenyl)-10,15,20-tris(p-methoxyphenyl)porphyrin

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments