Studies on Polymerization of a-Pinene Initiated by a New System AlCl3/Activator/Donors (Ⅰ)--AlCl3/SbCl3/Ester Initiating System

Abstract

Abstract: The new initiating system AlCl₃/A/D (Aas the activator, modifier and complex agent for Aids; Das the donors) for the polymerization of a-pinene was studied. It was found that some of these initiating systems have a high activity for cationic polymerization of a-pinene and give a good yield of a-pinene resin with high molecular weights. For example, the AlCl₃/SbCl₃/ethyl benzoate (EB) initiating system gives the yield 87. 3% of resin with S. P. 128, 8℃ in toluene at-15-25℃.In this paper, the kinetic behavior of these initiating systems and the characteristic of polymerization products are studied. The effects of various donors, the amount of SbCl₃added, solvents, temperatures and concentrations of EB, initiator and monomers on the polymerization of a-pinene are investigated.

Key words: New initiator, α-Pinene, Cationic polymerization

TrendMD:

Deng Yun-xiang, Lin Hua-yu, Higashimura T.. Studies on Polymerization of a-Pinene Initiated by a New System AlCl₃/Activator/Donors (Ⅰ)--AlCl₃/SbCl₃/Ester Initiating System[J]. Chem. J. Chinese Universities, 1991, 12(10): 1414.

[1]	YANG Wei-Jun, GUO Can-Cheng, MAO Yan-Li, LI Guo-Cheng. Catalysis and Substituent Effects of Monomanganese-porphyrins and Monoiron-porphyrins for α-Pinene Oxidation with Air [J]. Chem. J. Chinese Universities, 2005, 26(9): 1690.
[2]	SONG Zhi-Guang, LI Jing, LIU Qing-Wen, LI Ye-Zhi, HUANG Hua-Min. Baeyer-Villiger Reaction of(+)-Chrysanthenone [J]. Chem. J. Chinese Universities, 2005, 26(12): 2264.
[3]	SONG Zhi-Guang, LI Jing, LIU Qiang-Wen, LI Ye-Zhi, HUANG Hua-Min. Baeyer-Villiger Reaction of (+)-Chrysanthenone [J]. Chem. J. Chinese Universities, 2005, 26(12): 2264.
[4]	PANG Lai-Xing, ZENG Zhao-Hua, YANG Jian-Wen, CHEN Yong-Lie . Thermal Polymerization of Urethane Vinyl Ethers Initiated by Diaryldiodonium Salt [J]. Chem. J. Chinese Universities, 2004, 25(11): 2153.
[5]	LU Jiang, LIANG Hui, ZHANG Rong-Fu. Living Cationic Polymerization of β-Pinene with1-Phenylethyl Chloride/TiCl₄/Ti(OiPr)₄ [J]. Chem. J. Chinese Universities, 2000, 21(12): 1932.
[6]	GUO Wen-Li, LI Shu-Xin, MA Yu-Hong, XU Rui-Qing, WU Guan-Ying. Complexation Competition in Cationic Polymerization with TiCl₄ Coinitiator [J]. Chem. J. Chinese Universities, 1998, 19(4): 642.
[7]	CAO Xian-Yi, ZHOU Xin-Ru, CHU Guang-Cheng, WU Guan-Ying. Carbocationic Reaction Between 2, 4, 4-Trimethy 1-2-chloropentane and 1, 1-Diphenyl Ethylene(Ⅰ)──Main Features of the Reaction [J]. Chem. J. Chinese Universities, 1997, 18(2): 329.
[8]	DENG Yun-Xiang, PENG Chao-Pan, DUAN Wen, ZHANG Ren-Jun, ZENG Long-Mei. Studies on the Cationic Copolymerization of α-Pinene and Styrene with the AlCl₃ /SbCl₃ Catalyst [J]. Chem. J. Chinese Universities, 1996, 17(9): 1467.
[9]	LU Jiang, LIANG Hui, ZHANG Ren-Jun, DENG Yun-Xiang. Cationic Polymerization of α-Pinene Initiated by AlCl₃/SbCl₃──Studies on the Nature or the Initiating Species [J]. Chem. J. Chinese Universities, 1996, 17(8): 1314.
[10]	CAO Xian-Yi, WANG Qiang, WU Guang-Ying . Controlled Terminationof Isobutylene Cationic Polymerization──The Transformation of Reactive End [J]. Chem. J. Chinese Universities, 1995, 16(9): 1485.
[11]	DENG Yun-Xiang, PENG Chao-Pan, LIU Ping, ZHANG Ren-Jun, ZENG Long-Mei. Studies on the Microozonization-TLC Method for the Separation and Analysis of Copolymerization Products of α-Pinene/Styrene [J]. Chem. J. Chinese Universities, 1995, 16(8): 1306.
[12]	GUO Wen-Li, XU Rui-Qing, WU Guan-Ying . Cationic Polymerization of IBVE Initiated by Cl₂ TiCl₄/Toluene (Ⅰ)—Initiating Centers and the Role of Their Complex Competition in the Polymerization [J]. Chem. J. Chinese Universities, 1993, 14(10): 1460.
[13]	CAO Xian-Yi, ZHANG Chuan-Bai, WU Guan-Ying . Carbocationic Polymerization of Isobutylene by the Initiator System of Diethyl Aluminium Chloride/Benzyl Chloride/Pyridine [J]. Chem. J. Chinese Universities, 1993, 14(10): 1476.
[14]	DENG Yun-Xiang, ZHANG Ren-Jun, LU Jiang, LIU Shi-Nan, Toshinobu Higashimura. Studies on Polymerization of α-Pinene Initiated by a New System AlCl₃/Activator/Donors(Ⅲ)——Function of the SbCl₃ Component in the System [J]. Chem. J. Chinese Universities, 1993, 14(1): 130.
[15]	Deng Yun-xiang, Lin Hua-yu, Ma Qing-yun, Fan Shi-yan, Higashimura T.. Studies on Polymerization of a -Pinene Initiated by a New System AlCl₃/Activator/Donors(Ⅱ)--Studies on Polymer of α-Pinene and Polymerization Mechanism [J]. Chem. J. Chinese Universities, 1991, 12(11): 1559.

Studies on Polymerization of a-Pinene Initiated by a New System AlCl₃/Activator/Donors (Ⅰ)--AlCl₃/SbCl₃/Ester Initiating System

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments