Studies on Complex of Copper (Ⅱ) α-Methylacrylate with 2,2'-Bipyridine

Chem. J. Chinese Universities ›› 1991, Vol. 12 ›› Issue (10): 1297.

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Studies on Complex of Copper (Ⅱ) α-Methylacrylate with 2,2'-Bipyridine

Wang Yao-yu, Gao Yi-ci, Zhu Ying, Shi Qi-zhen

Department of Chemstry, Lanzhou University, Lanzhou, 730000

Received:1990-07-10 Online:1991-10-24 Published:1991-10-24

Abstract

Abstract: A detailed synthesis is described for complex of copperα-methylacrylate with 2,2'-bipyridine. Elementary analysis, thermal analysis, conductivity data, susceptibility, IRand UV-vis spectra indicate the complex as [Cu(CH₂=C(CH₃)COO)₂(bipy)(H₂O)]. The molecular structure of the title compound was determined by single crystal X-ray diffraction. The crystal is a monoclinic and the lattice parameters are: α=0. 6851(1) nm, 6=1. 7626(2) nm, c=1. 5553(1) nm,β=96. 52 (1)°.

Key words: Copper α-Methylacrylate, 2,2'-Bipyridine, Ternary complex

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Wang Yao-yu, Gao Yi-ci, Zhu Ying, Shi Qi-zhen . Studies on Complex of Copper (Ⅱ) α-Methylacrylate with 2,2'-Bipyridine[J]. Chem. J. Chinese Universities, 1991, 12(10): 1297.

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Studies on Complex of Copper (Ⅱ) α-Methylacrylate with 2,2'-Bipyridine

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