Studies on Chelate Reaction of New Fluorescent Reagent SPAEC with Gallium (Ⅲ) and Its Analytical Application

Abstract

Abstract: Anew fluorescent analytical reagent 2-(5'-sulfo-2'-hydroxyl-1'-phenylazo)-5-ethy-lamino-4-cresol(SPAEC), which has been synthesized recently in our laboratory, was applied to the fluorimetric determination of gallium. The optimal conditions for fluorescent complex formation of SPAECwith gallium ( M ) were established. At pH 3. 8-5. 5, a 1 : 1 type complex was formed with λ_ex/λ_em of 515/585 nm and with quantum yield (φ_F) of 0. 046. The proposed method was used for the determination of 2 × 10^-7～2 × 10^-6 mol/Lgallium in semiconductor and alloy samples with good results.

Key words: Fluorescent reagent SPAEC, Fluorimetry, Determination of gallium

TrendMD:

Li Zhiliang, Yu Ruqin . Studies on Chelate Reaction of New Fluorescent Reagent SPAEC with Gallium (Ⅲ) and Its Analytical Application[J]. Chem. J. Chinese Universities, 1990, 11(7): 689.

[1]	FENG Feng, CHEN Ze-Zhong, LIN Jie-Diao. Application of the Combination of the Drops Fluorimetry Sensor with the Computer in the Microanalysis [J]. Chem. J. Chinese Universities, 2004, 25(S1): 82.
[2]	CHEN Xiao-Lan, LI Dong-Hui, YANG Huang-Hao, ZHU Qing-Zhi, ZHENG Hong, XU Jin-Gou . Studies on Tetra-substituted Amino Aluminum Phthalocyanine as a New Red-region Substrate for Mimetic Peroxidase [J]. Chem. J. Chinese Universities, 2001, 22(7): 1120.
[3]	YANG Xiao-Feng, GUO Xiang-Qun . A Novel Fluorescence Probe for the Determination of Hydroxyl Radicals [J]. Chem. J. Chinese Universities, 2001, 22(3): 396.
[4]	XIE Jian-Wei, ZHAI Yan-Qiang, YANG Zao-Ping, RUAN Jin-Xiu. Chiral Recognition of Cyclodextrin Supramolecular System──Simultaneous Fluorescence Determination of D,L-Tryptophan Enantiomer by Chiral Recognition of β-Cyclodextrin [J]. Chem. J. Chinese Universities, 1997, 18(9): 1447.
[5]	TANG Bo, ZHANG Sheng-Yi, JIANG Chong-Qiu, ZHANG Xiao-Gang, LI Yan. Synthesis of Salicylaldehyde-5-bromo-salicylo and Its Fluorescence Reaction with Scandium [J]. Chem. J. Chinese Universities, 1997, 18(6): 883.
[6]	LI Yao-Qun, SHI Ning, QIAN Fang, HUANG Xian-Zhi. Simultaneous Determination of Fluorene, Acenaphthene,Anthracene and Perylene by Derivative Constant Energy Synchronous Fluorimetry [J]. Chem. J. Chinese Universities, 1997, 18(4): 538.
[7]	XU Yan, SHEN Han-Xi, HUANG Han-Guo. The Fluorescence Characterdistics of Complexes of Nalidixic Acid with Alkali Earth Metals and Its Application [J]. Chem. J. Chinese Universities, 1996, 17(2): 211.
[8]	JIANG Chong-Qiu, TANG Bo, FU Nong-Yan, CAO Hong, ZHANG Xiao-Gang. Studies on Fluotimetrid Reaction of Salicylaldehyde Benzalhydrazone with Copper and Its Application [J]. Chem. J. Chinese Universities, 1996, 17(1): 49.
[9]	ZHU Li-Zhong, QI Zhi-Hong, JIN Hui, QI Wen-Bin. Enhancement of the Fluorescence of Zn(Ⅱ)-Morin Complex by Ionic β-Cyclodextrins and Its Analytical Application [J]. Chem. J. Chinese Universities, 1995, 16(11): 1694.
[10]	ZHANG Gui-Zhu, ZHANG Hai-Qing, HE Xi-Wen, SHI Hui-Ming. Dual System and Dual Wavelength Fluorimetric Method and Its Use in Pharmaceutical Analysis [J]. Chem. J. Chinese Universities, 1995, 16(1): 43.
[11]	TANG Bo, HE Xi-Wen, SHEN Han-Xi, LI Feng-Zhen, GAO Chuan-Xi. Studies on the Three Kinds of Vitamins B Group Using Derivative-Synchronous Fluorimetry [J]. Chem. J. Chinese Universities, 1994, 15(7): 970.
[12]	ZHENG Yong-Xi, FAN Ying-Xin. Micelle-Sensitized Fluorometric Determination of Zirconium and Its Application [J]. Chem. J. Chinese Universities, 1994, 15(1): 35.
[13]	ZHU Yuan-Bao, WANG Ke-Min, XU Yuan-Jin, HE Shuang-E, LI Xun . Studies on a New Fluorescence Fiber Optic Sensor for Sulfur Dioxide [J]. Chem. J. Chinese Universities, 1993, 14(4): 476.
[14]	YANG Jing-He, ZOU Hua-Bin, JIE Nian-Qin, GE Hong-Mei . A Study of the Fluorescence System of Tetracycline-Eu-TOPO-Sodium Dodecyl Sulfonate System and the Determination for Tetracycline [J]. Chem. J. Chinese Universities, 1993, 14(3): 339.
[15]	GUO Xiang-Qun, XU Jin-Gou, ZHAO Yi-Bing, CHEN Guo-Zhen . Studies on Photochemical Fluorimetric Method(Ⅸ)——Determination of Menadione in Vitamin K₃ Injection by in situ Photochemical Fluorimetry [J]. Chem. J. Chinese Universities, 1992, 13(9): 1199.

Studies on Chelate Reaction of New Fluorescent Reagent SPAEC with Gallium (Ⅲ) and Its Analytical Application

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments