Studies on Electrochemical Polymerization of Acetylene

Chem. J. Chinese Universities ›› 1990, Vol. 11 ›› Issue (4): 431.

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Studies on Electrochemical Polymerization of Acetylene

Huan Zhengwei, Qiao Yinan, Yang Guang, Shen Zhiquan, Hu Shizhao, Zhou Xiaoxia

Department of Chemistry, Zhejitmg University, Hangzhou

Received:1988-07-22 Online:1990-04-24 Published:1990-04-24

Abstract

Abstract: Fe-doped polyacetylene film was prepared successfully on a stainless steel cathode by gal-vanostatic polymerization method at room temperature in Fe(NO₃)₃·9H₂O-DMFsolution. The various factors affecting the polymerization process were investigated. Instrumental analyses show that the configuration of the film is mainly trans-(CH)_z doped with Fe ca. 10% and the morphology of the film is polycrystals with a net texture.

Key words: Polyacetylene, Fe-doped polyacetylene, Galvanostatic polymerization

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Huan Zhengwei, Qiao Yinan, Yang Guang, Shen Zhiquan, Hu Shizhao, Zhou Xiaoxia . Studies on Electrochemical Polymerization of Acetylene[J]. Chem. J. Chinese Universities, 1990, 11(4): 431.

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Studies on Electrochemical Polymerization of Acetylene

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