Chem. J. Chinese Universities ›› 1990, Vol. 11 ›› Issue (4): 367.

• Articles • Previous Articles     Next Articles

A Study on the Thin-Layer Chromatography and Ultraviolet Spectrum of Dicyclo-pentadienyl Ytterbium and Dysprosium o-Substitutied Benzole Acid Derivatives

Li Songlan1, Yang Xuejin1, Sun Cheng1, Liang Shusen1, Ye Zhongwen2   

  1. 1. Department of Chemistry, Nankai University, Tianjin;
    2. Department of Chemistry, Aukui Normal University, Wuhu
  • Received:1988-10-26 Online:1990-04-24 Published:1990-04-24

Abstract: The thin-layer chromatography behavior of dicyclopentadienyl ytterbium and dysprosium o-substituted benzoic acid derivatives is studied using silica gel Gplate impregnated with decane. The following rules have been obtained:1. The Rf values are decreased as the increasing of the electron donating ability of o-substituting group in the aromatic ring.2. The silica gel plate impregnated with decane diminishes the absorbing activity only, but has no effect on the behavior of absorption chromatography.3. The Rf values change in the opposite direction with the λmax, values of ultraviolet spectrum for the series of compounds. The preliminary discussion is also made for this relationship in theory.

Key words: Modified thin layer plate, Ultraviolet spectrum R band, Mutual relationship

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