Chem. J. Chinese Universities ›› 1990, Vol. 11 ›› Issue (1): 78.
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Zhang Guomin, Jiang Fengchao, Zhang Lun
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Abstract: In this work , the reactioin of KBH4 with C5H5FeC5H4CH2NMe2(R)Xin aqueous solution is investigated. It is found that when Ris an electron-drawing group, the product is a quaternary ammonium salt of BH4- when Ris an electron-donating group or H , the product is a complex of BH3. The compositions of the products were identified by elemental analyses and IRspectrometry. The reaction provides a simple , high-yield synthetic procedure for quaternary ammonium salts of BH4- and complexes of borane.
Key words: Ferrocene derivatives, Borane complexes, Quaternary ammonium salts
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Zhang Guomin, Jiang Fengchao, Zhang Lun . Studies on Boron Compounds (ⅩⅩⅢ)—Reaction of Potassium Tetrahydroborate with Ferrocenylmethyl Trihydrocarbyl Ammonium Chlorides[J]. Chem. J. Chinese Universities, 1990, 11(1): 78.
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