Chem. J. Chinese Universities ›› 1989, Vol. 10 ›› Issue (5): 522.

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The Cobalt(Ⅱ) Complexes of Bis(n-octylsulfinyl)-ethane

Zhang Ruohua, Zhang Qiuwen. Zhang Zijing   

  1. Department of Chemistry, Nankai University, Tianjin
  • Received:1987-08-28 Online:1989-05-24 Published:1989-05-24

Abstract: Four cobalt( Ⅱ ) complexes of bis(n-octylsulfinyl)ethane have been perpared. These complexes have been characterized by elemental analysis, molar conductance, visible near-infrared, infrared spectra and molar susceptibility. They have the following formula [Co(α-BOSE)3](ClO4)2, [Co2(β-BOSE)5(ClO4)2](ClO4)<2·4H2O,[Co(α-BOSE)2(NO3)2],[Co(β-BOSE)(NO3)·H2O]NO3.The ligand field parameters of complexes and other data are also shown.

Key words: Bis(n-octylsulfinyl)ethane, Cobalt(Ⅱ ) complex

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