Chem. J. Chinese Universities ›› 1989, Vol. 10 ›› Issue (4): 431.

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The Extraction Kinetics of Cobalt (Ⅱ) Thiocyanate with Primary Amine N1923 by Growing Drop Method

Sun Sixiu, Gao Zili, Gai Huifa, Liu Yuanjun, Shen Jinglan   

  1. Department of Chemistry, Shandong University, Jinan
  • Received:1987-09-11 Online:1989-04-24 Published:1989-04-24

Abstract: The forward initial rate of the extraction of cobalt(Ⅱ) thiocyanate with primary amine N1923 was measured by means of the growing drop method at 25 ± 1℃.The effect of the temperature on the extraction rate was also investigated. The experimental results show that the rate-determining step of the .extraction process may be the following interfacial reactions:The activation energy of the process was calculated to be 15.1 kJ·mol-1.

Key words: Extraction kinetics, Primary amine N1923, Cobalt( Ⅱ) thiocyanate, Cobalt(Ⅱ)

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