XPS Studies of Tetraphenyl-2-Nitro-porphyrin Metal Complexes

Chem. J. Chinese Universities ›› 1989, Vol. 10 ›› Issue (2): 173.

• Articles • Previous Articles Next Articles

XPS Studies of Tetraphenyl-2-Nitro-porphyrin Metal Complexes

Wei Quan, Guan Yousheng, Cao Xizhang

Department of Chemistry, Jilin University, Changchun

Received:1987-07-27 Online:1989-02-24 Published:1989-02-24

Abstract

Abstract: The metal Complexes coordinated with tetrapbenyl porphyrin and tetraphenyl-2-nitroporphyrin were investigated by XPS. These metal complexes in which ions were mosaiced into big π system of conjugated ring structrue were demonstrated by π→π^* transition energy, transition probability and N_1tshift of binding energy. Furthermore, it was proved that -NO₃group is in conjunction with a pyrrole ring and this leads to an increase of Lewis acidity.

Key words: Porphyrin metal complexes, XPS, Electron effect

TrendMD:

Wei Quan, Guan Yousheng, Cao Xizhang . XPS Studies of Tetraphenyl-2-Nitro-porphyrin Metal Complexes[J]. Chem. J. Chinese Universities, 1989, 10(2): 173.

[1]	ZHANG Yong, FU Mao, WU Deli, ZHANG Yalei. Removal Performance and Mechanism of Selenite with the Highly Active Ferrous Hydroxyl Complex FHC(Cl^-)^† [J]. Chem. J. Chinese Universities, 2017, 38(5): 830.
[2]	SUN Er-Jun, WANG Dong, CHENG Xiu-Li, SHI Yu-Hua, SHI Tong-Shun. Preparation and Properties of 5,10,15,20-Tetra(4-myristylimidophenyl) Porphyrin and Its Zn and Mn Complexes [J]. Chem. J. Chinese Universities, 2007, 28(7): 1208.
[3]	ZHANG Ya-Nan^1,2, XIA Fan³, WANG Nü³, FENG Lin¹. Preparation and Characterization of Large-area Superhydrophobic Nanostructured Carbon Films [J]. Chem. J. Chinese Universities, 2007, 28(3): 568.
[4]	XIE Fu-Zhong¹, HU Hua-Rong¹, QIAO Ming-Hua¹, YAN Shi-Run¹, FAN Kang-Nian¹, LEI Hao², TAN Da-Li², BAO Xin-He², ZONG Bao-Ning³, ZHANG Xiao-Xin³. XPS Study on Adsorptive Desulfurization of Thiophene over Rapidly Quenched Skeletal Ni [J]. Chem. J. Chinese Universities, 2006, 27(9): 1729.
[5]	LI Ai-Ze, JIN Yu-Hui, LIU Bai-Jun, JIANG Zhen-Hua. Effect of Heat-treatment Atmosphere on the Near-infrared Absorption of the Fluorinated Poly(aryl ether) [J]. Chem. J. Chinese Universities, 2005, 26(6): 1177.
[6]	LI Hui, SHEN Fei, WU Chi-Fei. Preparation and Characterization of Novel NBR/PVC Alloy Crosslinked by Coordinate Bonds [J]. Chem. J. Chinese Universities, 2005, 26(2): 370.
[7]	LI Wan-Cheng, DU Guo-Tong, YANG Xiao-Tian, LIU Bo-Yang, ZHANG Yuan-Tao, ZHAO Bai-Jun, JIANG Xiu-Ying . XPS Valence Band of ZnO Films [J]. Chem. J. Chinese Universities, 2004, 25(11): 2078.
[8]	LI Xiao-Ling, XU Wei-Qing, JIA Hui-Ying, WANG Xu, ZHAO Bing, LI Bo-Fu . UV-Vis and XPS Spectroccopic Studies on Self-assembled Metalloporphrin Films [J]. Chem. J. Chinese Universities, 2004, 25(11): 2131.
[9]	YU Ji, CAN Hong-Yu, HE Yi, YUAN Juan, CHEN Huan-Lin. Studies on PVDF Hollow Fiber Affinity Membrane for Separation of γ-Globulin from Human Plasma(Ⅰ) -Preparation of PVDF Hollow Fiber Affinity Membrane and Its Adsorption Properties [J]. Chem. J. Chinese Universities, 2003, 24(5): 935.
[10]	DAI Wei-Lin, CAO Yong, FAN Kang-Nian, DENG Jing-Fa . In situ XPS Studies on the Anti-oxidation Effects of Nano-sized Ni-Co-B Amorphous Alloy [J]. Chem. J. Chinese Universities, 2003, 24(3): 473.
[11]	LI Li-Na, CHEN Yao-Qiang, GONG Mao-Chu, XIANG Yun . Catalytic Activity of Fe₂O₃/YSZ-γ-Al₂O₃for Methane Combustion [J]. Chem. J. Chinese Universities, 2003, 24(12): 2235.
[12]	SUN Bao-Yun, GU Zhen-Nan . Synthesis and Characterization of Water-soluble Metallofullerene Derivatives [J]. Chem. J. Chinese Universities, 2003, 24(10): 1747.
[13]	WU Xue-Yan, YOU Hong-Peng, ZENG Xiao-Qing, HONG Guang-Yan, KIM Chang-Hong, PYUN Chong-Hong, YU Byung-Yong, PARK Cheol-Hee. The Preparation of (La,Gd)PO₄:RE³⁺ (RE=Eu, Tb) by Co-precipitation Method and Their VUV Spectroscopic Properties [J]. Chem. J. Chinese Universities, 2003, 24(1): 1.
[14]	SONG Wei-Jie, ZHU Yong-Fa, CAO Li-Li, LI Zhan-Ping, WANG Dao-Yuan, Huang-Wei . Studies on Interface Structure of BBDMS-PPV/ITO System Using ADXPS Technique [J]. Chem. J. Chinese Universities, 2001, 22(5): 836.
[15]	LIU QingSheng, WANG ZhenLü, YU JianFeng, YANG PiaoPing, WANG GuoJia, YANG HongMao, ZHENG DaFang, WU TongHao. Investigation of Surface Structures of Supported ZnO/SiO₂ and ZnO-SiO₂ Sol-gel Catalysts [J]. Chem. J. Chinese Universities, 2001, 22(12): 2091.

XPS Studies of Tetraphenyl-2-Nitro-porphyrin Metal Complexes

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments