Chem. J. Chinese Universities ›› 1989, Vol. 10 ›› Issue (11): 1100.
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Zhu Shenjie, Gui Mingde, Guo Cancheng
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Abstract: The kinetic study on the conversion of (TPPFe)2Oto TPPFeCl is reported in this paper.In the presence of oxidant PhIOor H2O2 this conversion is first order for (TPPFe)2O, but in the presence of air this conversion is zero order for (TPPFe)2O.The temperature dependence of the rate constant is consistant with Arrhenius equation.Based on these results the probable mechanisms for this conversionare suggested.
Key words: (TPPFe)2O, TPPFeCl, Kinetics of the conversion
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Zhu Shenjie, Gui Mingde, Guo Cancheng . The Studies on the Conversion of μ-Oxo-bis(meso-tetraphenylporphinato) iron(Ⅲ) to Chloro(meso-tetraphenylporphinato) iron (Ⅲ) in CH2Cl2 with Oxidant[J]. Chem. J. Chinese Universities, 1989, 10(11): 1100.
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http://www.cjcu.jlu.edu.cn/EN/Y1989/V10/I11/1100
