Chem. J. Chinese Universities ›› 1988, Vol. 9 ›› Issue (9): 912.
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Liu Xingping, Wang Yongkeng, Li Shaobai, Pan Xinfu, Li Yulin, Huang Wenkui
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Abstract: In this wrok, ethyl cephalotaxinyl oxalate was prepared by ester exchange and the synthesis of the key intermediate, α-keto-acetyl-cephalotaxine, was achieved by treating this oxalate with a Grignard reagent. This constitutes an efficient modification of previously reported mathods for the synthesis of cephalotaxus este ralkaloids.
Key words: Ethyl cephalotaxmyl oxalate, α-Keto-acetyl-cephaltaxme
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Liu Xingping, Wang Yongkeng, Li Shaobai, Pan Xinfu, Li Yulin, Huang Wenkui . The Synthesis of Ethyl Cephalotaxinyl Oxalate and Its Application in the Synthesis of Cephalotaxus Ester Alkaloids[J]. Chem. J. Chinese Universities, 1988, 9(9): 912.
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http://www.cjcu.jlu.edu.cn/EN/Y1988/V9/I9/912